Synthesis and X-Ray Crystallographic Characterisation of Frustum-Shaped Ligated [Cu<sub>18</sub>H<sub>16</sub>(DPPE)<sub>6</sub>]<SUP>2+</SUP> and [Cu<sub>16</sub>H<sub>14</sub>(DPPA)<sub>6</sub>]<SUP>2+</SUP> Nanoclusters and Studies on Their H<sub>2</sub> Evolution Reactions