Electrical and Electronic Engineering - Research Publications

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    Visible to Short-Wave Infrared Photodetectors Based on ZrGeTe4 van der Waals Materials
    Yan, W ; Johnson, BC ; Balendhran, S ; Cadusch, J ; Yan, D ; Michel, JI ; Wang, S ; Zheng, T ; Crozier, K ; Bullock, J (AMER CHEMICAL SOC, 2021-09-29)
    The self-terminated, layered structure of van der Waals materials introduces fundamental advantages for infrared (IR) optoelectronic devices. These are mainly associated with the potential for low noise while maintaining high internal quantum efficiency when reducing IR absorber thicknesses. In this study, we introduce a new van der Waals material candidate, zirconium germanium telluride (ZrGeTe4), to a growing family of promising IR van der Waals materials. We find the bulk form ZrGeTe4 has an indirect band edge around ∼0.5 eV, in close agreement with previous theoretical predictions. This material is found to be stable up to 140 °C and shows minimal compositional variation even after >30 days storage in humid air. We demonstrate simple proof-of-concept broad spectrum photodetectors with responsivities above 0.1 AW-1 across both the visible and short-wave infrared wavelengths. This corresponds to a specific detectivity of ∼109 cm Hz1/2 W-1 at λ = 1.4 μm at room temperature. These devices show a linear photoresponse vs illumination intensity relationship over ∼4 orders of magnitude, and fast rise/fall times of ∼50 ns, also verified by a 3 dB roll-off frequency of 5.9 MHz. As the first demonstration of photodetection using ZrGeTe4, these characteristics measured on a simple proof-of-concept device show the exciting potential of the ZrGeTe4 for room temperature IR optoelectronic applications.
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    Copper Tetracyanoquinodimethane (CuTCNQ): A Metal-Organic Semiconductor for Room-Temperature Visible to Long-Wave Infrared Photodetection
    Balendhran, S ; Hussain, Z ; Shrestha, VR ; Cadusch, J ; Ye, M ; Azar, NS ; Kim, H ; Ramanathan, R ; Bullock, J ; Javey, A ; Bansal, V ; Crozier, KB (AMER CHEMICAL SOC, 2021-08-18)
    Mid-wave and long-wave infrared (MWIR and LWIR) detection play vital roles in applications that include health care, remote sensing, and thermal imaging. However, detectors in this spectral range often require complex fabrication processes and/or cryogenic cooling and are typically expensive, which motivates the development of simple alternatives. Here, we demonstrate broadband (0.43-10 μm) room-temperature photodetection based on copper tetracyanoquinodimethane (CuTCNQ), a metal-organic semiconductor, synthesized via a facile wet-chemical reaction. The CuTCNQ crystals are simply drop-cast onto interdigitated electrode chips to realize photoconductors. The photoresponse is governed by a combination of interband (0.43-3.35 μm) and midgap (3.35-10 μm) transitions. The devices show response times (∼365 μs) that would be sufficient for many infrared applications (e.g., video rate imaging), with a frequency cutoff point of 1 kHz.
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    Visible to Long-Wave Infrared Photodetectors based on Copper Tetracyanoquinodimethane (CuTCNQ) Crystals
    Balendhran, S ; Hussain, Z ; Shrestha, VR ; Cadusch, J ; Ye, M ; Kim, H ; Ramanathan, R ; Bullock, J ; Javey, A ; Bansal, V ; Crozier, KB (OSA - Optical Society of America, 2020-08-01)
    We demonstrate room-temperature photodetectors at wavelengths from visible (450 nm, 532 nm) to near- (850 nm), short-wave (1550 nm), mid-wave (4.5 \mu m) and long-wave (8.35 \mu m) infrared. These are based on drop-cast Cu TCNQ crystals.