School of Physics - Research Publications
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ItemNo Preview AvailableSpeckle and Conservation(International Seminars, 2008)The aim of this research is to demonstrate the usefulness of speckle, a trait of an expanded laser beam, for the non-destructive testing of artwork in both the imaging of subsurface structure and the quantitative detection of physical movement of canvas. Laser Speckle Contrast Method (LSCI) is a useful method for the viewing of subsurface layers and movement. By investigating the statistical properties of dynamic speckle it is possible to reveal drawings that are hidden beneath scattering layers such as the primary layer of paint or adhered paper. This is achieved by taking a series of speckle images captured in a short time frame and applying one of a number of post processing algorithms. We explore the limitations of this method when applied to various paper samples that have a sketch executed in various media beneath the top layer. The ability to resolve gray scale images was examined as well as looking at the dependence of the contrast of the revealed drawings to the temperature of the surface. Current work is being done on using LSCI to reveal indentations in artwork caused by the application process. The successful use of Electronic Speckle Pattern Interferometry (ESPI) both in the laboratory and in-situ for the detection of in-plane movement of painted canvas due to humidity fluctuations and the out-of-plane movement of paint as it dries has also been demonstrated. Canvas paintings can be very susceptible to movement due to changes of the environment. ESPI is a non-destructive technique yielding sensitive results that can detect displacement on a surface of less than the wavelength of the illuminating coherent light source. While ESPI has been successfully applied to the in-situ study of painted frescoes, previous studies have employed tensile testers as a support for painted canvas. We have shown a portable version of ESPI to be of use in tropical environment in the Philippines, Malaysia and Singapore with original artworks where variations in humidity occur and the samples have not undergone special preparation before analysis, revealing significant directional movements. Furthermore, a simple variation in the direction of beams paths permits the characterisation of out-of-plane movement, specifically as the height of paint shrinks due to the drying process. We have used ESPI to view the drying process of alkyd resin paints over the time period of 24 hours.
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ItemDirect Assembly of Large Area Nanoparticle Arrays(AMER CHEMICAL SOC, 2018-08)A major goal of nanotechnology is the assembly of nanoscale building blocks into functional optical, electrical, or chemical devices. Many of these applications depend on an ability to optically or electrically address single nanoparticles. However, positioning large numbers of single nanocrystals with nanometer precision on a substrate for integration into solid-state devices remains a fundamental roadblock. Here, we report fast, scalable assembly of thousands of single nanoparticles using electrophoretic deposition. We demonstrate that gold nanospheres down to 30 nm in size and gold nanorods <100 nm in length can be assembled into predefined patterns on transparent conductive substrates within a few seconds. We find that rod orientation can be preserved during deposition. As proof of high fidelity scale-up, we have created centimeter scale patterns comprising more than 1 million gold nanorods.
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ItemTuning of Plasmonic Resonances in the Near Infrared Spectrum Using a Double Coaxial Aperture Array(IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC, 2018-12)
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ItemDirected Chemical Assembly of Single and Clustered Nanoparticles with Silanized Templates(AMER CHEMICAL SOC, 2018-06-26)The assembly of nanoscale materials into arbitrary, organized structures remains a major challenge in nanotechnology. Herein, we report a general method for creating 2D structures by combining top-down lithography with bottom-up chemical assembly. Under optimal conditions, the assembly of gold nanoparticles was achieved in less than 30 min. Single gold nanoparticles, from 10 to 100 nm, can be placed in predetermined patterns with high fidelity, and higher-order structures can be generated consisting of dimers or trimers. It is shown that the nanoparticle arrays can be transferred to, and embedded within, polymer films. This provides a new method for the large-scale fabrication of nanoparticle arrays onto diverse substrates using wet chemistry.
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ItemDirect Assembly of Large Area Nanoparticle Arrays( 2018-07-13)We describe the fabrication of large area arrays of single nanoparticles using electrophoretic deposition.
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ItemPlasmonics-enabled metal-semiconductor-metal photodiodes for high-speed interconnects and polarization sensitive detectors(SPIE-INT SOC OPTICAL ENGINEERING, 2017-01-01)Metal-semiconductor-metal (MSM) photodiodes are commonly used in ultrafast photoelectronic devices. Re- cently it was shown that localized surface plasmons can su_ciently enhance photodetector capabilities at both infrared and visible wavelengths. Such structures are of great interest since they can be used for fast, broadband detection. By utilizing the properties of plasmonic structures it is possible to design photodetectors that are sensitive to the polarization state of the incident wave. The direct electrical readout of the polarization state of an incident optical beam has many important applications, especially in telecommunications, bio-imaging and photonic computing. Furthermore, the fact that surface plasmon polaritons can circumvent the di_raction limit, opens up signi_cant opportunities to use them to guide signals between logic gates in modern integrated circuits where small dimensions are highly desirable. Here we demonstrate two MSM photodetectors integrated with aluminum nanoantennas capable of distinguishing orthogonal states of either linearly or circularly polarized light with no additional _lters. The localized plasmon resonances of the antennas lead to selective screening of the un- derlying silicon from light with a particular polarization state. The non-null response of the devices to each of the basis states expands the potential utility of the photodetectors while improving precision. We also demonstrate a design of waveguide-coupled MSM photodetector suitable for planar detection of surface plasmons.
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ItemHot-Carrier Organic Synthesis via the Near-Perfect Absorption of Light(AMER CHEMICAL SOC, 2018-11-01)Photocatalysis enables the synthesis of valuable organic compounds by exploiting photons as a chemical reagent. Although light absorption is an intrinsic step, existing approaches rely on poorly absorbing catalysts that require high illumination intensities to afford enhanced efficiencies. Here, we demonstrate that a plasmonic metamaterial capable of near-perfect light absorption (94%) readily catalyzes a model organic reaction with a 29-fold enhancement in conversion relative to controls. The oxidation of benzylamine proceeds via a reactive iminium intermediate with high selectivity at ambient temperature and pressure, using only low-intensity visible irradiation. Control experiments demonstrated that only hot charge carriers produced following photoexcitation facilitate the formation of superoxide radicals, which, in turn, leads to iminium formation. Modeling shows that hot holes with energies that overlap with the highest-occupied molecular orbital (HOMO) of the reactant can participate and initiate the photocatalytic conversion. These results have important implications for hot-carrier photocatalysis and plasmon-hot-carrier extraction.
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ItemOptical image processing with metasurface dark modes(OPTICAL SOC AMER, 2018-09-01)Here we consider image processing using the optical modes of metasurfaces with an angle-dependent excitation. These spatially dispersive modes can be used to directly manipulate the spatial frequency content of an incident field, suggesting their use as ultra-compact alternatives for analog optical information processing. A general framework for describing the filtering process in terms of the optical transfer functions is provided. In the case where the relevant mode cannot be excited with a normally incident plane wave (a dark mode), high-pass filtering is obtained. We provide examples demonstrating filtering of both amplitude and pure phase objects.
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ItemSwitchable polarization rotation of visible light using a plasmonic metasurface(AMER INST PHYSICS, 2017-01-01)A metasurface comprising an array of silver nanorods supported by a thin film of the phase change material vanadium dioxide is used to rotate the primary polarization axis of visible light at a pre-determined wavelength. The dimensions of the rods were selected such that, across the two phases of vanadium dioxide, the two lateral localized plasmon resonances (in the plane of the metasurface) occur at the same wavelength. Illumination with linearly polarized light at 45° to the principal axes of the rod metasurface enables excitation of both of these resonances. Modulating the phase of the underlying substrate, we show that it is possible to reversibly switch which axis of the metasurface is resonant at the operating wavelength. Analysis of the resulting Stokes parameters indicates that the orientation of the principal linear polarization axis of the reflected signal is rotated by 90° around these wavelengths. Dynamic metasurfaces such as these have the potential to form the basis of an ultra-compact, low-energy multiplexer or router for an optical signal.
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ItemMetasurfaces, dark modes, and high NA illumination(OPTICAL SOC AMER, 2018-10-15)The interaction of a focused beam with a metasurface supporting dark modes is investigated. We show computationally and experimentally that the excitation of dark modes is accompanied by characteristic changes in the reflected Fourier spectrum. This spatial frequency filtering capability indicates an avenue for the all-optical, on-chip detection of phase gradients for biological and other imaging techniques.