School of Physics - Research Publications
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ItemDirect Assembly of Large Area Nanoparticle Arrays(AMER CHEMICAL SOC, 2018-08)A major goal of nanotechnology is the assembly of nanoscale building blocks into functional optical, electrical, or chemical devices. Many of these applications depend on an ability to optically or electrically address single nanoparticles. However, positioning large numbers of single nanocrystals with nanometer precision on a substrate for integration into solid-state devices remains a fundamental roadblock. Here, we report fast, scalable assembly of thousands of single nanoparticles using electrophoretic deposition. We demonstrate that gold nanospheres down to 30 nm in size and gold nanorods <100 nm in length can be assembled into predefined patterns on transparent conductive substrates within a few seconds. We find that rod orientation can be preserved during deposition. As proof of high fidelity scale-up, we have created centimeter scale patterns comprising more than 1 million gold nanorods.
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ItemTuning of Plasmonic Resonances in the Near Infrared Spectrum Using a Double Coaxial Aperture Array(IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC, 2018-12)
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ItemDirected Chemical Assembly of Single and Clustered Nanoparticles with Silanized Templates(AMER CHEMICAL SOC, 2018-06-26)The assembly of nanoscale materials into arbitrary, organized structures remains a major challenge in nanotechnology. Herein, we report a general method for creating 2D structures by combining top-down lithography with bottom-up chemical assembly. Under optimal conditions, the assembly of gold nanoparticles was achieved in less than 30 min. Single gold nanoparticles, from 10 to 100 nm, can be placed in predetermined patterns with high fidelity, and higher-order structures can be generated consisting of dimers or trimers. It is shown that the nanoparticle arrays can be transferred to, and embedded within, polymer films. This provides a new method for the large-scale fabrication of nanoparticle arrays onto diverse substrates using wet chemistry.
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ItemDirect Assembly of Large Area Nanoparticle Arrays( 2018-07-13)We describe the fabrication of large area arrays of single nanoparticles using electrophoretic deposition.
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ItemPlasmonic Metasurfaces for Optical Information Processing(SPIE-INT SOC OPTICAL ENGINEERING, 2019-01-01)Optical spatial frequency filtering is a key method for information processing in biological and technical imaging. While conventional approaches rely on bulky components to access and filter the Fourier plane content of a wavefield, nanophotonic approaches for spatial frequency filtering have recently gained attention. Here computational and experimental progress towards the design and demonstration of metasurfaces with spatial frequency filtering capability for optical image processing will be presented. Using the example of a metasurface consisting of radial rod trimers we demonstrate its potential to perform edge enhancement in an amplitude image and conversion of phase gradients in a wavefield into intensity modulations. The presented results indicate a potential avenue for ultra-compact image processing devices with applications in biological live-cell imaging.
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ItemScalable and Consistent Fabrication of Plasmonic colors via Nanoimprint Lithography(SPIE-INT SOC OPTICAL ENGINEERING, 2019-01-01)We utilised thermal and UV-assisted Nanoimprint Lithography (NIL) i.e. thermal and UV-assisted to produce plasmonic coloration, and compare their ability for scalable fabrication. Several designs are presented and we show the generated colors are dependent on their geometry and the direction of polarisation of incident illumination. Finally, we demonstrated UV-NIL for consistent production of large-area (0.6×0.4 cm2) plasmonic color with extended color gamut.
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ItemTuning the asymmetric response of metasurfaces for optical spatial filtering(SPIE-INT SOC OPTICAL ENGINEERING, 2019-01-01)The spatial filtering of optical signals has been demonstrated previously with metasurface thin-films created from arrays of structured optical elements. We consider the problem of changing the symmetry of their response with changes to the in-plane wavevector kI→-kI and show it can be tailored or even dynamically tuned. Our work is based on a general theory of metasurfaces constructed from non-diffracting arrays of coupled metal particles. We present the optical transfer function of such a metasurface, identify the physical properties essential for asymmetry and demonstrate its behaviour experimentally.
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ItemUltracompact Camera Pixel with Integrated Plasmonic Color Filters(WILEY-V C H VERLAG GMBH, 2019-09-17)Photodetector size imposes a fundamental limit on the amount of information that can be recorded by an image sensor. Compact, high-resolution sensors are generally preferred for portable electronic devices such as mobile phones and digital cameras, and as a result, a significant effort has been invested in improving the image quality provided by small-area image sensors. Reducing photodetector size, however, still faces challenges in implementation requiring improvements in current technology to meet the demand for ultracompact imaging systems such as cameras. An issue with a decrease in size is associated with photodetectors utilizing color filters. In most commonly used camera designs these filters are made of dyes or pigments and incompatible with the complementary metal-oxide-semiconductor fabrication process. They are, therefore, fabricated in two different technological processes and require subsequent alignment. As the pixel size decreases, the alignment of these layers becomes challenging. Furthermore, dye-based filters need to have a thickness of the order of micrometers to ensure sufficient absorption. Here a compact, low-cost color sensor is proposed and experimentally demonstrated utilizing monolithically integrated plasmonic antennas that have a nanoscale thickness and are fabricated in the same technological process with photodetector matrix.
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ItemHot-Carrier Organic Synthesis via the Near-Perfect Absorption of Light(AMER CHEMICAL SOC, 2018-11-01)Photocatalysis enables the synthesis of valuable organic compounds by exploiting photons as a chemical reagent. Although light absorption is an intrinsic step, existing approaches rely on poorly absorbing catalysts that require high illumination intensities to afford enhanced efficiencies. Here, we demonstrate that a plasmonic metamaterial capable of near-perfect light absorption (94%) readily catalyzes a model organic reaction with a 29-fold enhancement in conversion relative to controls. The oxidation of benzylamine proceeds via a reactive iminium intermediate with high selectivity at ambient temperature and pressure, using only low-intensity visible irradiation. Control experiments demonstrated that only hot charge carriers produced following photoexcitation facilitate the formation of superoxide radicals, which, in turn, leads to iminium formation. Modeling shows that hot holes with energies that overlap with the highest-occupied molecular orbital (HOMO) of the reactant can participate and initiate the photocatalytic conversion. These results have important implications for hot-carrier photocatalysis and plasmon-hot-carrier extraction.
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ItemPlasmene Metasurface Absorbers: Electromagnetic Hot Spots and Hot Carriers(AMER CHEMICAL SOC, 2019-02-01)Light-matter interactions are extremely important, as they sustain life on Earth and can be tailored for diverse applications in areas such as solar energy conversion, chemical sensing, and information storage. One key process of these interactions is the absorption of photons. We demonstrate a novel material capable of absorbing up to 98% of incident visible light. The material comprises a thin sheet of a tightly packed two-dimensional lattice of metal nanoparticles, called plasmene, supported by a thin (subwavelength) dielectric film deposited on top of a mirror. We demonstrate how the resulting metasurface absorbers are useful in surface-enhanced spectroscopy and in the generation of plasmonic hot carriers. These structures hold great promise for applications in structural color, sensing, and photocatalysis.