School of Earth Sciences - Theses
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ItemThe Variation of atmospheric carbon dioxide,methane and nitrous oxide during the holocene from ice core analysis(University of Melbourne, 2004)Recent studies have demonstrated that the atmospheric concentrations of radiatively important greenhouse gases, including methane (CH4), carbon dioxide (CO2), nitrous oxide (N2O) and carbon monoxide (CO), have significantly increased during the past 200 years due to anthropogenic emissions. Analysis of air trapped in polar ice cores allows for past atmospheric variations due to natural climate conditions to be investigated, placing recent changes in a historical context. In this thesis new high- precision, multispecies measurements of atmospheric trace gas concentrations during the Holocene have been produced by analysing the air trapped in the ice at Law Dome, East Antarctica (66�46'08"E, 112�48�28�S). The ice core records are well-dated, have high age resolution and overlap with modem instrumental records due to the high accumulation rate at the drilling sites. The combination of high age resolution, precise dating and high precision measurements allows for subtle, decadal-scale variability to be detected. The multispecies measurement technique allows for biogeochemical causes of variations to be identified. The first part of this study focused on the late Holocene period (AD 0 to 1975). New high-precision records of CH4, CO2, N2O and CO have been produced for this period. The CH4 and CO2 measurements are used to build upon the existing Law Dome records of these gases during the last 1000 years, to validate and further define previously observed variations. The new measurements extend the records of these gases by another 1000 years. As a consequence of the multispecies measurement technique it has been possible to also measure N2O and CO during this period. These new measurements highlight the atmospheric response to the Little Ice Age (LIA) cooling (AD 1550 to 1800), particularly a 10 ppm decrease in atmospheric C02 between AD 1550 and 1600. A stabilization of CO2 during the 1940s was also confirmed in the Law Dome record. Increased data density during this period shows that the atmospheric CO2 mixing ratio stabilized at ~310 ppm between 1937 and 1955. New signals were observed in the extended records, including a 100 ppb increase in the CH4 concentration between AD 0 and 1800, which is probably the result of increasing pre-industrial anthropogenic emissions. The second part of this study focussed on the CO2 and CH4 response to a rapid, abrupt cooling at 8,200 years BP. The Law Dome (DSS) measurements are complemented by four measurements of NorthGRIP (Greenland) ice core. A decrease of at least 52 ppb CH4 is observed in the DSS record, and a decrease of at least 62 ppb is observed at NorthGRIP during the same period. A smaller CO2 response of 4 to 5 ppm is seen in both the records. The CH4 signal is used to improve the chronologies of these ice cores by synchronising with other well-dated CH4 records, specifically GRIP (Greenland) and Dome C (Antarctica).
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ItemThe structural evolution, tectonics and hydrocarbons of the offshore Otway Basin, SE Australia( 2003)The offshore Otway Basin is part of Australia's passive southern margin, in which two separate rift-phases between the Tithonian? and Maastrichtian formed numerous depocentres. The research presented has analyzed and described the structural styles in the offshore Otway Basin and constructed a model of the basin's evolution since the Late Jurassic. The Otway Basin has been divided into four structural zones from north to south. Zone I comprises the onshore area and most of the shelf along the margin. Deep halfgraben developed during the first rift phase with characteristic horst and graben in Palaeozoic basement. To the south, zone I is bound by the Hinge Zone. Structural zone II covers the entire deepwater part of the Otway margin, characterized by a very thick Late Cretaceous section with pervasive Turonian faulting in the east and saucer-shaped depocentres in the west. Large halfgraben controlled deposition of the post-Turonian sedimentation in the eastern Otway Basin. Negative flower structures document strike-slip faulting. Strongly thinned lower laminated continental crust underlies this zone, limited to the south by the Outer Margin Highs. Domino faulting formed halfgraben and less commonly graben in Structural Zone III, the Outer Margin Highs. The base of the Outer Margin High sediments represents a regional decollement surface and domino faulting occurred along a second-generation decollement. Structural zone III is limited to the south by the continent-ocean-boundary with oceanic crust in structural zone IV. In the Shipwreck Trough, halfgraben died out against an accommodation zone which developed into the Shipwreck Fault with strike-slip offset .The regional stress regime indicate sinistral strike-slip movement along this fault zone. In the southwest Shipwreck Trough, four Turonian to early Coniacian syn-rift phases can be distinguished formed through footwall collapse to the north of the Hinge Zone. Differences in the amount of extension in the basin are accommodated along strike-slip faults such as the Shipwreck Fault. Sedimentation rates between 89 and 83 Ma increased whilst extension rates declined. Since approximately 83Ma sedimentation rates declined exponentially in phase with extension rates. Regionally, rapid Turonian extension formed a wide graben system between Antarctica and Australia. With the serpentinization of exhumed mantle peridotite in the Outer Margin Highs during the Coniacian in the east and Turonian in the west, the crustal deformation mechanism changed from mainly pure shear to simple shear along the newly established decollement. Fast spreading since the Mid Eocene caused gravitational collapse of the margin. Changes in heat flow possibly correlate with a change in deformation style in the continental crust. Parallel developments of sedimentation-rate and extension-rate suggest that most of the subsidence was structurally related. The Shipwreck Trough hydrocarbon fairway probably continues south into the Sorrell Basin. Possible stagnant conditions in deeper water offshore across the Hinge Zone might have enhanced the organic content of the Belfast Mudstone creating potential oil source rocks. Deepwater lntra-Paaratte reservoirs are not proven, but the alternating reflective to non-reflective seismic facies might indicate interbedded sands and shales. Large rollover anticlines would make excellent traps in the deepwater Otway Basin.
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ItemThe weather and climate of Australia at the Last Glacial Maximum( 2005)The global climate has experienced four glacial cycles in the last 420,000 years, with each cycle characterised by a prolonged period of cooling culminating in maximal glaciation followed by a brief warm period. The most recent period of maximal glaciation is termed the Last Glacial Maximum (LGM) and occurred about 21,000 years ago. We currently live in one of the warm periods. The global climate is changing, and it is becoming more important to understand the extremes of the climate system and how well our modelling capability can capture those extremes. There has been a modelling intercomparison project established to examine how global general circulation models compare in simulating past climates, including the LGM. Analysis and comparison of these model results has been presented for many parts of the globe, but there has not been a comparison of the different model results over the Australian region. This thesis aims to fill that gap and explore the simulated LGM weather and climate of Australia and its drivers in more detail. Comparison with proxy evidence is also undertaken, and inconsistencies seen in the literature addressed. The Australian climate at the LGM was believed to be generally cooler, drier and possibly windier from proxy evidence in the literature. In the comparison done here the mean temperature and precipitation fields from most models show cooler and drier conditions, with some seasonal variability, but there are some strong outliers. It was found that the differences were not dependent on model resolution, but that the surface parameterisations were highly important for these fields. The shifts in the circulation were examined both in the model results and with a study of the non-linear link between the wind, surface moisture and dunes, which are a proxy for past winds. All the models simulate a southward shift in the westerlies in the Australian region. This is strongly driven byte prescribed sea-surface temperatures. Australia's current wind regime is conducive to dune building. However, the binding effect of soil moisture (or vegetation) is strong enough to limit present day movement, whereas in the drier climate at the LGM there was a capacity for sand movement. The analysis of dune orientations did not produce conclusive evidence for how the westerlies might have shifted at the LGM. An apparent enigma in the proxy evidence at the LGM is the high lake levels in Australia’s south east, while most inland lakes were dry. Previous authors believed that the precipitation was still low, but the high lake levels were driven by lowered potential evaporation. The hydrological cycle was generally depressed in the LGM simulations, but the potential for evaporation remained high. Thus an alternative hypothesis is posed based on increased run off due to a known shift in the vegetation types and a lag in the timing of the run off due to snowmelt. The analysis here shows that our capacity to simulate climates quite different from the present is still developing, but that model results can help explain apparent inconsistencies in the reconstruction of past climates from proxies.
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ItemThe hydrogeology of the Gippsland Basin, and its role in the genesis and accumulation of petroleum( 2002)The Gippsland Basin of southeastern Australia is the most energy-rich basin of Australia producing petroleum, gas and brown coal. Three-quarters of the Basin lies offshore and the rest onshore. The basin was initiated as a rift valley, caused by the separation of the Australian continent from the Antarctic followed by a number of tectonic events throughout the basin history. Early Cretaceous sedimentary rocks form the basement, which is in turn covered with Late Cretaceous to Recent sediment of sand, clay, limestone, and brown coal seams. The total thickness of the in-filling sediments offshore attains up to 6000 m, but onshore is up to 1200 m. There are three main acquifer systems, the Hydrostratigraphic Units 2, 4, and 7, all of which are confined. The two lower aquifer systems, Units 4 and 7, contain high temperature groundwater. It is generally agreed that the hydrocarbons offshore have been derived from terrestrial matters including brown coal and ligneous clay offshore. In the present study, the author has developed a case that hydrocarbons offshore being derived not only from the offshore source but also from onshore brown coals and coaly matter and in this hydrocarbon forming processes, groundwater has played a significant role. The Central Deep, in particular, provides favourable conditions for hydrocarbon maturation. Throughout the basin history, the Central Deep has experienced the oil window temperatures. In supporting this hypothesis, geochemical studies on groundwater, brown coal, and hydrocarbons as well as hydrodynamics are presented.
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ItemThe tectonic history of the Ruker Province, southern Prince Charles Mountains, East Antarctica: implications for Gondwana and Rodinia( 2006-12)Within the Ruker Province of East Antarctica, there is evidence for several key geological events that have occurred coincidently with periods of dynamic earth evolution. A detailed evaluation of the tectonic history of the region is therefore required. This research focuses on the tectonic development of the Ruker Province. The main aspects of this research can be summarised as follows: (1) an evaluation of the gross crustal architecture of the region through the development of a new stratigraphic and structural framework; (2) new U-Th-Pb (LA-ICPMS) age data from detrital zircon grains extracted from thick metasedimentary units that comprise a major component of the Ruker Province; (3) new 40Ar/39Ar data from metamorphic minerals to determine the cooling history of the province; (4) mineral equilibria modelling of metamorphic mineral assemblages to constrain pressure-temperature (P-T) conditions during key orogenic events; (5) a kinematic analysis of brittle/ductile deformation features. Ideas developed from these new data provide inferences on the assembly and dispersion of the late Proterozoic super-continents Rodinia (c. 1000 Ma) and Gondwana (c. 500 Ma).
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ItemA new perspective on melt inclusions: development of novel in-situ analytical protocols( 2006-08)Novel techniques for in-situ lead isotope analysis of melt inclusions using multicollector inductively coupled plasma mass spectrometry, and parallel Faraday cup and ion counter detection have been developed. These provide for measurement of the critical 204Pb isotope, which has been unavailable in melt inclusion Pb isotope studies, but requires on-line determination of 200Hg to correct for 204Hg isobaric interferences. External standardisation allows for effective mass fractionation correction and ion counter gain calibration. An off-line Tau correction was applied and standard glass analyses suggest that this correction provides more accurate and precise results.
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ItemContinental tectonics and landscape evolution in south-central Australia and southern Tibet( 2006-09)The Indo-Australian Plate is actively deforming at its margins and within its interior. In south-central Australia, more than 3000 km from the closest active plate boundary, a geomorphically rugged and apparently youthful mountain range has developed, rising up to 1.1km above the adjacent flat-lying outback plains. These ‘Flinders’ and ‘Barrier’ Ranges are seismically active and bound by major reverse fault scarps with clear evidence for Plio-Quaternary displacements, implying that young and active intraplate tectonism has played a fundamental role in their development. Palaeoseismic investigations and optically stimulated luminescence (OSL) chronology indicate faulting occurred in response to a series of large magnitude (~M6.6 to M7.3) palaeo-earthquakes with recurrence intervals of ~1:20,000 to~1:80,000 yrs and long-term fault slip rates of ~50 m Myr-1. Geomorphic observations and 10Becosmogenic nuclide dating indicate surprisingly high and spatially variable rates of bedrock erosion from fault-affected catchments in the Flinders Ranges. Slowly eroding bedrock summit surfaces have been uplifted up to 12 m in the last 60,000-100,000 years relative to more rapidly eroding valley floors and bounding piedmonts, indicating Late Quaternary increases in elevation and relief in response to intraplate tectonism and erosion. However, both facies changes and sediment aggradation-dissection cycles in alluvial fan sequences are out-of-synch within dividual tectonic events, indicating that an aspect of climate (aridification, changing flood frequency-magnitude distributions) has governed the spatial-temporal distribution of range front sedimentation.
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ItemGlobal changes in synoptic activity with increasing atmospheric CO2( 2005-11)Over the last century, increases in anthropogenic greenhouse gases and global temperature in the atmosphere has drawn our attention to changes in extra tropical cyclones which influence daily weather patterns in the mid and high latitudes and redistribute energy, momentum and moisture across the globe. This study is aimed at examining changes in extra tropical cyclones: observed over the past two decades using the NCEP-DOE reanalysis II data (NCEP2); and simulated in the CSIRO Mark2 atmosphere-ocean coupled general circulation model (GCM) with increasingCO2. Furthermore, we attempt to explore the physical mechanisms driving such changes by modelling idealised experiments with the Melbourne University atmospheric GCM. The Melbourne University cyclone finding and tracking scheme is utilised to detect and track cyclones observed in NCEP2 and simulated in the two models. The study demonstrates significant changes in Southern Hemisphere (SH) cyclone features from 1979-2000. SH cyclones have decreased in their number at the surface but increased at the 500 hPa level. On the other hand, SH cyclone physical features such as intensity, radius and depth have significantly increased over the two decades at the mean sea level and 500 hPa level. Moreover, cyclones became vertically better organized in both hemispheres, and particularly in the SH. The changes in the characteristics of Northern Hemisphere (NH) cyclones were statistically less significant than their SH counterparts in the period of 1979-2000. Results from the coupled climate model simulation with enhanced CO2 suggest general reductions in cyclone frequency and intensity throughout the troposphere between the surface and500 hPa level but increases in cyclone radius and organization of vertical structure. These changes are persistent throughout the entire transient run with increasing CO2 and during a 100 year stabilisation period. It is found in the CSIRO simulation with enhanced CO2 that the geographical changes of cyclone features are similar in both hemispheres and between the surface and 500 hPa level. Furthermore, we conclude that some observed changes in extra tropical cyclone features seem to follow the patterns of simulated changes with increasing CO2 from 1xCO2 to 2xCO2 particularly in the SH. Modelling latitudinal temperature gradient at different levels of the troposphere has revealed that the warming over the tropics at the upper troposphere causes cyclone frequency and depth to increase in the high latitudes but decrease in the mid latitudes. By contrast, the warming over the high latitudes at the lower troposphere results in decreases in the cyclone features in the high latitudes but increases in them in the mid latitudes. Therefore, the warming over the tropics seems to play an important role in the changes in SH summer cyclone frequency and depth appearing in the simulation with enhanced CO2, whereas the warming over both tropics and high latitudes affects the changes in SH winter cyclone features. In the NH, the change in latitudinal temperature gradient seems less influential in the changes of cyclone features than it does in the SH.
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ItemThe low-temperature thermochronology of cratonic terranes( 2006)Cratonic terranes present many problems for geologists attempting to define those regions of the continental crust that are the core of today's continents. Inherent in the term is the great passage of time, and typically, the term defines consolidated Archaean or Proterozoic crust (Park and Jaroszewski, 1994). Cratons are further distinguished on the basis of tectonic activity. Marshak and his colleagues (1999) suggest that the lack of penetrative deformation or metamorphism is a useful definition but they further narrow this with the restriction of a Precambrian timeframe. Central to either view is the assumption of stability and perhaps senescence. And, since many aspects of geological research involve the detection of stratigraphic, structural or mineralogical change, stability implies a lack, or at least a minimum, of change. Thus the absence of these traditional markers of geological evolution or change, related to these processes, presents significant challenges in the study of cratons. This is particularly so in shield areas - those cratons with exposed basement rocks (Park and Jaroszewski, 1994). The extraordinary age of shield rocks and their apparent preservation at the surface, has encouraged research into the mechanics of landscape development and the individual evolution of landforms in the landscape, particularly by geomorphologists. From within this environment many thought provoking ideas have been proposed to explain the breadth of observations pertaining to almost every aspect of landscape process in these terranes. According to Summerfield (1991) the models of Davis, Penck, King and Budel have had the most impact in this field. The ideas presented by these workers remain a cornerstone in our understanding of the earth's surface, but in detail and in practice, the models have been shown to be antiquated. Nevertheless, landform evolution models such as those of L.C. King (1967) have held sway in southern Africa and elsewhere long after the underlying assumptions have been shown to lack validity. The purpose of this thesis is to investigate key aspects of landscape evolution in two regions, central Australia and southern Africa, where models have been espoused, arguing for extraordinary surface stability or alternatively a simple erosional history or pediplanation. Contemporary thermochronological techniques now permit us to investigate these regions in previously unavailable detail. The primary technique used in this work was apatite fission track analysis and an introduction to the fundamentals of the method is given in Chapter 1. The theoretical and practical aspects of the fission track method provided the basis for an innovative approach presented in Chapter 2. TASC is a scheme for analysing the raw fission track data so as to extract additional information about the rock's thermal history prior to undertaking traditional inverse modelling techniques. This method (recently described by the author in Ehlers et al., 2005) proved to be a powerful complement to the routine fission track analysis undertaken as part of the Australian and African case studies. Although first proposed for geological use in the 1960's, the fission track technique really only gained serious application with a number of technical and theoretical breakthroughs in the 1980's. Since then, growing understanding of the processes of annealing and how they might be modelled has allowed the technique continue developing. Chapter 3 is a discussion of this topic that expands on material previously published by the author and colleagues (Gleadow et al., 2002) and presents additional new work. Nevertheless, despite it's wide application in tectonic and basin studies amongst others, there remain many improvements to be made and problems to be solved. As part of this project, research into several areas presented the author with opportunities to contribute toward improvement in the apatite fission track technique, that have the potential to aid the study of cratonic terranes. The chlorine content of apatite has a profound influence on the sensitivity of the mineral for recording thermal events. Few current annealing models are capable of comprehensively addressing the variation of chlorine and other trace elements that appear to play a role in the annealing process. This issue is addressed in Chapter 4 where a universal annealing model is proposed to deal with the wide chemical variability observed in real apatites. For this theme, a fresh consideration of established empirical mathematical models was undertaken and all the current published annealing data was considered. Modern inverse modelling is based on a series of robust, but nonetheless empirical, equations that have withstood the test of time. However, with the aim of developing a more realistic and thus predictive model, Chapter 5 introduces an alternative, physicochemical to modelling the thermal annealing of fission tracks. This work attempts to draw firmer links between the processes of fission track formation, the mechanics of diffusion and the predicted response to variable temperature regimes. The first of the case studies is presented in Chapter 6 and is a comprehensive investigation of the long-term landscape evolution of the Davenport Ranges in the central Australian Craton. The study employs traditional petrographic methods as well as thermochronology and combines cosmogenic isotope analysis in an assessment of early landscape models. This chapter expands on work previously published by the author and co-workers (Belton et al., 2004) and has implications for our understanding of landscape evolution in the broader context of the Australian Craton. In order to maximise temperature sensitivity in slow cooled terranes, the relatively new thermochronological technique of (U-Th)/Helium analysis of apatite was tested on a suite of central Australian samples. The inconclusive results of this experiment prompted an investigation into the possible causes, and an important baseline study was conducted (Chapter 7). The study has implications for routine application of this new thermochronometer in cratonic and other terranes. More importantly the research identified a potential new thermochronometer with an even greater temperature sensitivity and near surface application for use in future landscape studies. Chapter 8 documents a larger, craton-wide study of the Mesozoic to recent landscape evolution of the Zimbabwe Craton. This work builds on material presented in earlier chapters and provides a broader view of the nature of crustal cooling, structural reactivation and landform development in the cratonic setting of southern Africa.
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ItemThe thermotectonic evolution of the northern precambrian shield, Western Australia( 2002)Reconnaissance 40Ar/39Ar dating of K-feldspars and muscovites, and fission track and (U-Th)/He thermochronometry on apatites has been applied to ~1 X 106 km2 of the northern Western Australian Shield. The study area includes the Archaean northern Yilgarn Craton and Pilbara Craton, and the intervening Proterozoic basins. The geomorphology of the study area also reveals a subdued relief, which is characteristic for Australian cratonic landscapes. The fact that the shield consists entirely of Precambrian rocks with low topographic relief has led to the widely held view that the West Australian Shield has been tectonically stable for a long period of time. (From Abstract)