School of Earth Sciences - Theses
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ItemThe Variation of atmospheric carbon dioxide,methane and nitrous oxide during the holocene from ice core analysis(University of Melbourne, 2004)Recent studies have demonstrated that the atmospheric concentrations of radiatively important greenhouse gases, including methane (CH4), carbon dioxide (CO2), nitrous oxide (N2O) and carbon monoxide (CO), have significantly increased during the past 200 years due to anthropogenic emissions. Analysis of air trapped in polar ice cores allows for past atmospheric variations due to natural climate conditions to be investigated, placing recent changes in a historical context. In this thesis new high- precision, multispecies measurements of atmospheric trace gas concentrations during the Holocene have been produced by analysing the air trapped in the ice at Law Dome, East Antarctica (66�46'08"E, 112�48�28�S). The ice core records are well-dated, have high age resolution and overlap with modem instrumental records due to the high accumulation rate at the drilling sites. The combination of high age resolution, precise dating and high precision measurements allows for subtle, decadal-scale variability to be detected. The multispecies measurement technique allows for biogeochemical causes of variations to be identified. The first part of this study focused on the late Holocene period (AD 0 to 1975). New high-precision records of CH4, CO2, N2O and CO have been produced for this period. The CH4 and CO2 measurements are used to build upon the existing Law Dome records of these gases during the last 1000 years, to validate and further define previously observed variations. The new measurements extend the records of these gases by another 1000 years. As a consequence of the multispecies measurement technique it has been possible to also measure N2O and CO during this period. These new measurements highlight the atmospheric response to the Little Ice Age (LIA) cooling (AD 1550 to 1800), particularly a 10 ppm decrease in atmospheric C02 between AD 1550 and 1600. A stabilization of CO2 during the 1940s was also confirmed in the Law Dome record. Increased data density during this period shows that the atmospheric CO2 mixing ratio stabilized at ~310 ppm between 1937 and 1955. New signals were observed in the extended records, including a 100 ppb increase in the CH4 concentration between AD 0 and 1800, which is probably the result of increasing pre-industrial anthropogenic emissions. The second part of this study focussed on the CO2 and CH4 response to a rapid, abrupt cooling at 8,200 years BP. The Law Dome (DSS) measurements are complemented by four measurements of NorthGRIP (Greenland) ice core. A decrease of at least 52 ppb CH4 is observed in the DSS record, and a decrease of at least 62 ppb is observed at NorthGRIP during the same period. A smaller CO2 response of 4 to 5 ppm is seen in both the records. The CH4 signal is used to improve the chronologies of these ice cores by synchronising with other well-dated CH4 records, specifically GRIP (Greenland) and Dome C (Antarctica).
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ItemThe structural evolution, tectonics and hydrocarbons of the offshore Otway Basin, SE Australia( 2003)The offshore Otway Basin is part of Australia's passive southern margin, in which two separate rift-phases between the Tithonian? and Maastrichtian formed numerous depocentres. The research presented has analyzed and described the structural styles in the offshore Otway Basin and constructed a model of the basin's evolution since the Late Jurassic. The Otway Basin has been divided into four structural zones from north to south. Zone I comprises the onshore area and most of the shelf along the margin. Deep halfgraben developed during the first rift phase with characteristic horst and graben in Palaeozoic basement. To the south, zone I is bound by the Hinge Zone. Structural zone II covers the entire deepwater part of the Otway margin, characterized by a very thick Late Cretaceous section with pervasive Turonian faulting in the east and saucer-shaped depocentres in the west. Large halfgraben controlled deposition of the post-Turonian sedimentation in the eastern Otway Basin. Negative flower structures document strike-slip faulting. Strongly thinned lower laminated continental crust underlies this zone, limited to the south by the Outer Margin Highs. Domino faulting formed halfgraben and less commonly graben in Structural Zone III, the Outer Margin Highs. The base of the Outer Margin High sediments represents a regional decollement surface and domino faulting occurred along a second-generation decollement. Structural zone III is limited to the south by the continent-ocean-boundary with oceanic crust in structural zone IV. In the Shipwreck Trough, halfgraben died out against an accommodation zone which developed into the Shipwreck Fault with strike-slip offset .The regional stress regime indicate sinistral strike-slip movement along this fault zone. In the southwest Shipwreck Trough, four Turonian to early Coniacian syn-rift phases can be distinguished formed through footwall collapse to the north of the Hinge Zone. Differences in the amount of extension in the basin are accommodated along strike-slip faults such as the Shipwreck Fault. Sedimentation rates between 89 and 83 Ma increased whilst extension rates declined. Since approximately 83Ma sedimentation rates declined exponentially in phase with extension rates. Regionally, rapid Turonian extension formed a wide graben system between Antarctica and Australia. With the serpentinization of exhumed mantle peridotite in the Outer Margin Highs during the Coniacian in the east and Turonian in the west, the crustal deformation mechanism changed from mainly pure shear to simple shear along the newly established decollement. Fast spreading since the Mid Eocene caused gravitational collapse of the margin. Changes in heat flow possibly correlate with a change in deformation style in the continental crust. Parallel developments of sedimentation-rate and extension-rate suggest that most of the subsidence was structurally related. The Shipwreck Trough hydrocarbon fairway probably continues south into the Sorrell Basin. Possible stagnant conditions in deeper water offshore across the Hinge Zone might have enhanced the organic content of the Belfast Mudstone creating potential oil source rocks. Deepwater lntra-Paaratte reservoirs are not proven, but the alternating reflective to non-reflective seismic facies might indicate interbedded sands and shales. Large rollover anticlines would make excellent traps in the deepwater Otway Basin.
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ItemEnvironmental fate and transport of TNT in soil at the former explosives factory Maribyrnong( 2002)Highly toxic explosives compounds can potentially contaminate soil and groundwater and pose extended environmental hazard due to their persistence. Explosives contamination within soils was investigated at the former Explosives Factory at Maribyrnong (EFM), by sampling and spectrophotometric / HPLC analysis. The environmental fate and transport of 2,4,6-trinitrotoluene (TNT) was assessed via batch and microcosm testing to quantify the influence of key subsurface sinks, adsorption, and transformation, and hence evaluate natural attenuation as a remediation option. A five tonne crystalline TNT source zone was delineated within soils at the base of a TNT process waste lagoon. This source was found to be supplying aqueous TNT loading to subsurface soils and groundwater, with the resultant plume localised to the shallow clay sequence due to a combination of natural attenuation processes and hydrogeological constraints. Freundlich described sorptive partitioning was found to be the main TNT sink at EFM (KF= 29 mL/g), while transformation rates were moderate (3.86 x 10-4 hr-1) due to aerobic conditions, and TNT toxicity inhibiting microbial degradation. Slow groundwater migration toward the Maribyrnong River (0.7 m/yr) and upward hydraulic gradients within underlying sand and gravel aquifers serve to increase TNT residence time within the clay aquitard, leading to increased interaction with adsorptive substrates and microbes and/or elements of the soil matrix responsible for aerobic transformation. Remediation of the contaminated lagoon may involve removal and treatment/landfilling of the top 1m of soil, then refilling with an impermeable capping allowing ongoing natural attenuation of residual TNT at depth via anaerobic degradation and sorption.
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ItemThe origin of the South Australian Heat Flow Anomaly( 2007)The South Australian Heat Flow Anomaly is a zone of high surface heat flow (averaging 92 ± 10 mW m-2); one of several central Australian Proterozoic terranes rich in heat producing elements (HPEs). Its bulk crustal average heat production is between two and three times the global average, indicating an enormous regional enrichment of uranium, thorium and potassium. Until now the distribution of HPEs in the crust has been calculated based on surface heat production; here, a method that uses the temperature at the Moho (as calculated by seismic inversion models) is introduced and found to have good agreement with models that assume a single enriched layer in the upper crust. This layer is found to be between 15-20km. The onset of recycling of uranium through the crust and mantle at the end of the Archaean has been proposed to have produced a peak in uranium available to crust-building, at least partially contributing to the creation of a long-lived geochemical anomaly in Central Australia. However analysis of lead isotopes of K-feldspars from the SAHFA indicates that at the time that crust was first extracted from the mantle, thorium was enriched relative to uranium (not vice versa). In order to investigate more recent effects of such high heat flow, the Tertiary cooling history of the Mt. Painter Inlier is investigated using (U-Th-Sm)/He thermochronology, which has a closure temperature of ~70°C. The most recent ages recorded are ~38 ± 5 Ma, and are argued to record burial of 1400 ± 200m under basement and Cretaceous sediment.
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ItemAustralian Neoproterozoic glaciation: a study of the Sturtian glacial deposits in the Arkaroola region, Northern Flinders Ranges South Australia( 2005)The late Proterozoic Sturtian glacigenic succession exposed in the Arkaroola region of the Northern Flinders Ranges record the earliest of two global Neoproterozoic `Snowball' glacial events in the Adelaide Geosyncline, South Australia. Two stratigraphically disparate glacigenic units were recognised in the late Sturtian succession in the Arkaroola region, a subaerially deposited glacial till - the Merinjina Tillite, and an unclassified glaciomarine diamict unit. The Merinjina Tillite unit preserves a five-fold lithostratigraphy, hosting englacial melt-out deposits, glaciolacustrinal sediments and dominated by a massive to poorly-bedded tillite unit deposited directly from glacier ice. The glaciomarine diamictite preserves down-slope mass-flow deposits, as well as turbidite sequences, slumping and sediments from glacial fall-out including dropstones embedded in laminated muddy-shale and is interpreted as a basin-margin marine deposit. Palaeocurrent analyses across the Northern Flinders Ranges and stratigraphic reviews of analogous Sturtian glacigenic deposits elsewhere in the Northern Flinders Zone suggest palaeotidal influence from the north-north-west and indicate a north-north-west-sloping basin margin in the Northern Flinders Zone. Two major palaeoclimatic phases were recognised in glacigenic rocks the Arkaroola region. A glacial advance phase is represented by the advance of continental glacial sediments, across a topographically-elevated, subaerial surface and extending down-slope into a submarine basin. The other, represented regionally by dropstone shales, is interpreted as glacial retreat and the termination of Sturtian `Snowball Earth' conditions. A rise in palaeo-atmospheric temperatures is inferred, causing melting of continental and marine ice-sheets and resulting in a regionally-extensive marine transgression. The slight increase in water temperature during glacial retreat is believed to have triggered carbonate precipitation and the ultimate deposition of cap dolomites which overly the glacigenic sediments across the Adelaide Geosyncline.
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ItemThe weather and climate of Australia at the Last Glacial Maximum( 2005)The global climate has experienced four glacial cycles in the last 420,000 years, with each cycle characterised by a prolonged period of cooling culminating in maximal glaciation followed by a brief warm period. The most recent period of maximal glaciation is termed the Last Glacial Maximum (LGM) and occurred about 21,000 years ago. We currently live in one of the warm periods. The global climate is changing, and it is becoming more important to understand the extremes of the climate system and how well our modelling capability can capture those extremes. There has been a modelling intercomparison project established to examine how global general circulation models compare in simulating past climates, including the LGM. Analysis and comparison of these model results has been presented for many parts of the globe, but there has not been a comparison of the different model results over the Australian region. This thesis aims to fill that gap and explore the simulated LGM weather and climate of Australia and its drivers in more detail. Comparison with proxy evidence is also undertaken, and inconsistencies seen in the literature addressed. The Australian climate at the LGM was believed to be generally cooler, drier and possibly windier from proxy evidence in the literature. In the comparison done here the mean temperature and precipitation fields from most models show cooler and drier conditions, with some seasonal variability, but there are some strong outliers. It was found that the differences were not dependent on model resolution, but that the surface parameterisations were highly important for these fields. The shifts in the circulation were examined both in the model results and with a study of the non-linear link between the wind, surface moisture and dunes, which are a proxy for past winds. All the models simulate a southward shift in the westerlies in the Australian region. This is strongly driven byte prescribed sea-surface temperatures. Australia's current wind regime is conducive to dune building. However, the binding effect of soil moisture (or vegetation) is strong enough to limit present day movement, whereas in the drier climate at the LGM there was a capacity for sand movement. The analysis of dune orientations did not produce conclusive evidence for how the westerlies might have shifted at the LGM. An apparent enigma in the proxy evidence at the LGM is the high lake levels in Australia’s south east, while most inland lakes were dry. Previous authors believed that the precipitation was still low, but the high lake levels were driven by lowered potential evaporation. The hydrological cycle was generally depressed in the LGM simulations, but the potential for evaporation remained high. Thus an alternative hypothesis is posed based on increased run off due to a known shift in the vegetation types and a lag in the timing of the run off due to snowmelt. The analysis here shows that our capacity to simulate climates quite different from the present is still developing, but that model results can help explain apparent inconsistencies in the reconstruction of past climates from proxies.
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ItemThe hydrogeology of the Gippsland Basin, and its role in the genesis and accumulation of petroleum( 2002)The Gippsland Basin of southeastern Australia is the most energy-rich basin of Australia producing petroleum, gas and brown coal. Three-quarters of the Basin lies offshore and the rest onshore. The basin was initiated as a rift valley, caused by the separation of the Australian continent from the Antarctic followed by a number of tectonic events throughout the basin history. Early Cretaceous sedimentary rocks form the basement, which is in turn covered with Late Cretaceous to Recent sediment of sand, clay, limestone, and brown coal seams. The total thickness of the in-filling sediments offshore attains up to 6000 m, but onshore is up to 1200 m. There are three main acquifer systems, the Hydrostratigraphic Units 2, 4, and 7, all of which are confined. The two lower aquifer systems, Units 4 and 7, contain high temperature groundwater. It is generally agreed that the hydrocarbons offshore have been derived from terrestrial matters including brown coal and ligneous clay offshore. In the present study, the author has developed a case that hydrocarbons offshore being derived not only from the offshore source but also from onshore brown coals and coaly matter and in this hydrocarbon forming processes, groundwater has played a significant role. The Central Deep, in particular, provides favourable conditions for hydrocarbon maturation. Throughout the basin history, the Central Deep has experienced the oil window temperatures. In supporting this hypothesis, geochemical studies on groundwater, brown coal, and hydrocarbons as well as hydrodynamics are presented.
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ItemThe tectonic history of the Ruker Province, southern Prince Charles Mountains, East Antarctica: implications for Gondwana and Rodinia( 2006-12)Within the Ruker Province of East Antarctica, there is evidence for several key geological events that have occurred coincidently with periods of dynamic earth evolution. A detailed evaluation of the tectonic history of the region is therefore required. This research focuses on the tectonic development of the Ruker Province. The main aspects of this research can be summarised as follows: (1) an evaluation of the gross crustal architecture of the region through the development of a new stratigraphic and structural framework; (2) new U-Th-Pb (LA-ICPMS) age data from detrital zircon grains extracted from thick metasedimentary units that comprise a major component of the Ruker Province; (3) new 40Ar/39Ar data from metamorphic minerals to determine the cooling history of the province; (4) mineral equilibria modelling of metamorphic mineral assemblages to constrain pressure-temperature (P-T) conditions during key orogenic events; (5) a kinematic analysis of brittle/ductile deformation features. Ideas developed from these new data provide inferences on the assembly and dispersion of the late Proterozoic super-continents Rodinia (c. 1000 Ma) and Gondwana (c. 500 Ma).
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ItemA new perspective on melt inclusions: development of novel in-situ analytical protocols( 2006-08)Novel techniques for in-situ lead isotope analysis of melt inclusions using multicollector inductively coupled plasma mass spectrometry, and parallel Faraday cup and ion counter detection have been developed. These provide for measurement of the critical 204Pb isotope, which has been unavailable in melt inclusion Pb isotope studies, but requires on-line determination of 200Hg to correct for 204Hg isobaric interferences. External standardisation allows for effective mass fractionation correction and ion counter gain calibration. An off-line Tau correction was applied and standard glass analyses suggest that this correction provides more accurate and precise results.
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ItemContinental tectonics and landscape evolution in south-central Australia and southern Tibet( 2006-09)The Indo-Australian Plate is actively deforming at its margins and within its interior. In south-central Australia, more than 3000 km from the closest active plate boundary, a geomorphically rugged and apparently youthful mountain range has developed, rising up to 1.1km above the adjacent flat-lying outback plains. These ‘Flinders’ and ‘Barrier’ Ranges are seismically active and bound by major reverse fault scarps with clear evidence for Plio-Quaternary displacements, implying that young and active intraplate tectonism has played a fundamental role in their development. Palaeoseismic investigations and optically stimulated luminescence (OSL) chronology indicate faulting occurred in response to a series of large magnitude (~M6.6 to M7.3) palaeo-earthquakes with recurrence intervals of ~1:20,000 to~1:80,000 yrs and long-term fault slip rates of ~50 m Myr-1. Geomorphic observations and 10Becosmogenic nuclide dating indicate surprisingly high and spatially variable rates of bedrock erosion from fault-affected catchments in the Flinders Ranges. Slowly eroding bedrock summit surfaces have been uplifted up to 12 m in the last 60,000-100,000 years relative to more rapidly eroding valley floors and bounding piedmonts, indicating Late Quaternary increases in elevation and relief in response to intraplate tectonism and erosion. However, both facies changes and sediment aggradation-dissection cycles in alluvial fan sequences are out-of-synch within dividual tectonic events, indicating that an aspect of climate (aridification, changing flood frequency-magnitude distributions) has governed the spatial-temporal distribution of range front sedimentation.