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    Mobility of base metals through regolith, Broken Hill, N.S.W.
    Lulofs, Damien ( 1993)
    Regolith profiles over and around zones of Pb-Zn mineralisation were investigated at Maybell and Stirling Vale, located in the Broken Hill region, N.S.W. Metasediments and metavolcanics of the Proterozoic Willyama Supergroup crop out in the study areas, with quartz-gahnite horizons hosting mineralisation. Desert loam soils in the study areas have a transported origin. Locally transported sheetwash deposits overlie a relict aeolian deposit which sits on relatively fresh Proterozoic bedrock. Mineralogy of the regolith profile is consistent with depth and landscape position. Quartz-gahnite horizons form topographic highs in both areas, containing up to 13.5% Zn. Gossanous material is associated with the quartz-gahnite rocks. No base metal containing secondary minerals were present in this weathered material but there were high proportions of iron oxides containing substantial amounts of base metals. Surrounding soils were anomalous in Zn, Cu and their pathfinders Cd and As, which outlines a mobilisation of base metals. Similar anomalies were expressed in stream sediments. Calcrete in the area, contained no anomalous levels of Zn, due to the low solubility of Zn at high pH. The majority of base metals in soils were associated with amorphous iron oxides and silicates (presumably gahnites). These metal bonding sites indicate, dispersion haloes in the regolith are due to a combination of physical and chemical dispersion. In this example of transported regolith profiles in an arid terrain, Zn and Cu are both physically and hydromorphically dispersed from weathering quartz-gahnite horizons.