School of Earth Sciences - Theses
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ItemHydromorphology of within-channel river benches( 2008)The fluvial morphology of a river channel is a function of the river’s hydrologic and sediment regime. Within-channel river benches are a fluvial feature widely identified in the international literature as geomorphically and ecologically important. Despite this recognition the relationship between bench morphology and the flow regime is poorly understood. The aim of this thesis is to identify the components of the flow regime responsible for the formation and destruction of within-channel benches. Opinions on the formative flows for benches are highly varied with reports that benches are formed by flows which just inundate the bench; to low-flow periods and sub-bankfull flows; bankfull flows and the annual flood; and moderate, medium and catastrophic sized floods. A large body of research also treats benches as a static morphology. Opinions on destructive flows are similarly varied. There is little empirical evidence for these suggestions. A bench is most commonly referred to as comprising a horizontal (planar) surface which results from within-channel deposition, but the term is also used to describe bars, floodplains and erosional features. The inability of researchers to agree on the relationships between bench morphology and river hydrology is influenced by the lack of a consistent definition and classification for benches. To adequately address the aim this thesis is presented in two parts: Part A addresses bench nomenclature and provides a sound basis for Part B which addresses the processes of bench formation and destruction. (for complete abstract open document)
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ItemPhysical and chemical hydrogeology of the Otway Basin, southeast Australia( 2009)The Otway Basin of southeast Australia is the subject of this thesis, which incorporates pre-existing geological, hydraulic and major element hydrogeological data with new isotope hydrogeochemical investigations. The region is an Upper Cretaceous–Tertiary basin, filled with siliciclastic and calcareous aquifers and aquitards and characterised by late volcanic activity, pervasive faulting and karstification. (For complete abstract open document.) As part of this study, an hydrogeological database is compiled for the Otway Basin region from existing distinct datasets from the states of Victoria and South Australia. Utilising this new resource, the data are reinterpreted into a 3D model of the hydrostratigraphy for the basin in GoCAD, and interpolated surfaces of hydraulic head and electrical conductivity are created for 5 aquifers/aquitards. The Victorian hydraulic head data is analysed for long term declining or inclining trends and hydrograph trend maps are created for different aquifer systems. The data are also compiled into representative cross sections of flow and chemical composition, with one section located in each of the three major sub-basins. The records of groundwater chemistry from the Victorian section of the Otway Basin are used to plot the relative concentration of major cations and anions for the main aquifers. More than 120 groundwater samples were taken for analysis of major and minor ion concentration and/or oxygen, hydrogen, carbon, strontium and chlorine isotope composition. These data are used to characterise the hydrogeochemical evolution of the groundwater and to identify the processes that the groundwater drives or experiences in the system. The potentiometric maps and cross sections reveal the interconnected nature of the flow in all aquifers and the relationship between local and regional flow systems. Regional flow paths originate inland near basement highs or the basin margins. In the shallower aquifers they terminate at the coastline where the groundwater mixes with ocean water at a diffuse interface and density differences induce groundwater discharge at the land surface or the ocean floor. In the deeper confined aquifers, discharge is submarine via several possible mechanisms, which include: diffuse intergranular leakage to overlying units; flow along faults or volcanic conduits; and/or seepage directly to the ocean from exposed sections of the aquifer, e.g. in submarine canyons. These mechanisms may be operating up to 50 km offshore but the interface is currently migrating landward, which will result in a shortening of that estimated distance. Local-scale flow lines are complex and may be oriented against the direction of regional coastward flow. Local hydraulic divides are often associated with volcanic eruption centres, which have elevated topography and relatively high hydraulic head, making them important recharge zones. These zones contain low salinity groundwater because infiltration is relatively rapid. Conversely, basalt flows that have developed clay horizons through weathering reduce drainage and allow significant evapotranspiration which concentrates the cyclic salts in solution. Many local flow systems discharge mainly via evapotranspiration, which acts again to concentrate the cyclic salts in solution. Other local discharge zones are rivers, creeks and lakes or lagoons that receive baseflow and seeps and springs associated with geological contacts or boundaries and faults. Evaporitic concentration of solutes in surface water bodies and shallow groundwater affects the quality of water recharging the underlying aquifers and aquitards. This quality has changed over the last 50,000 years or so due to fluctuations in climate and hence variation of the precipitation/evaporation ratio. Stresses on the aquifers are climate fluctuations, sea level change, land use change and groundwater extraction. These stresses have resulted in the system being out of hydraulic equilibrium in many cases. Lags in response to these changes in boundary conditions are identified and/or hypothesised. In particular, the confined aquifer’s response to sea level change could be subject to a lag in the order of millennia. The stress on an aquifer is often transferred to its adjacent units, in some cases inducing cross-formational leakage, which is possibly supported by radiocarbon dating evidence. The area of the Otway Ranges appears to have escaped the effects of stress to date because of its stable microclimate, its distance from the ocean and from groundwater extraction. Increase in demand on groundwater resources, development of geothermal, sequestration and hydrocarbon industries and future climate change may yet have a detrimental effect on the groundwater of the Otway Basin. Isotopic composition of the groundwater confirms its meteoric origin and chlorine isotopes from several samples of the deep groundwater indicate that accumulation of solutes along the flow path is not due to diffusion or dissolution of connate salt. Thus, the salinity of the water is sourced from cyclic salts and solutes from water-rock interaction, both of which may be concentrated by evapotranspiration. Water-rock interaction is dominated by dissolution of carbonates and weathering of silicates as a result of the surficial geology being dominated by calcarenite or limestone and young basalt. The volcanic activity has produced gas that has interacted with the groundwater, and continues to do so, fractionating oxygen, hydrogen and carbon isotopes and contributing fluorine, boron and sulphur to solution. The addition of volcanic CO2 creates an uncommon situation for water-rock interaction, where continued dissolution of carbonate and silicate minerals along the deeper flow paths is demonstrated by the silicon/chloride ratios and strontium isotopic composition of the groundwater. These water-rock interaction processes, with the addition of cation exchange, are responsible for the development of a relatively fresh Na+HCO− 3 type water that is characteristic in parts of the deep aquifer. The study confirms the existing hydrogeological understanding of the Otway Basin and forms new conclusions regarding the history of the groundwater and the processes of flow and chemical evolution by integrating numerous lines of evidence. Significant contributions of this work which improve current scientific knowledge include these findings: the maps and cross sections of hydraulic head and electrical conductivity reveal the connected nature of flow systems within all the aquifers and aquitards; geological features can induce discharge, e.g. at contacts or faults, and recharge, e.g. volcanic eruption centres; the changes to the surface drainage system as a result of the eruption of basalt flows have affected the water chemistry and flow systems in all the underlying units; there is a lag in aquifers’ responses to sea level change and therefore future migration of the interface is expected regardless of further boundary changes; climate change has influenced surface water quality by changing the regional water balance, and therefore has affected groundwater quality; the discharge from the confined aquifer is submarine via various pathways, interaction between the groundwater and volcanic gas has occurred in the past and is ongoing, and consequently mineral dissolution persists at deep levels; the origin of high salinity of brackish groundwater in all Tertiary aquifers and aquitards is concentrated solutes from water rock interaction and cyclic deposition.
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ItemGeochronology of Timor-Leste and seismo-tectonics of the southern Banda Arc( 2009)Arc–continent collision is a significant plate boundary process that results in crustal growth. Since the early stages of evolution are often obscured in mature orogens, more complete understanding of the processes involved in arc–continent collision require study of young, active collision settings. The Banda Arc presents an exceptional opportunity to study a young arc–continent collision zone. This thesis presents aspects of the geology and geochronology of Ataúro and the Aileu Complex of Timor-Leste, and the tectonics of the Banda Arc. U–Pb dating of detrital zircons from the Aileu Complex by LA-ICPMS show major age modes at 270–440 Ma, 860–1240 Ma and 1460–1870 Ma. The youngest zircon populations indicate a maximum depositional age of 270 Ma. The detrital zircon age populations and evidence for juvenile sediments within the sequence favours a synorogenic setting of deposition of sediments sourced from an East Malaya – Indochina terrane. Previous uncertainty in aspects of the cooling history for the Aileu Complex is resolved with 39Ar/40Ar geochronology of hornblende. Cooling ages of 6–10 Ma are established, with the highest metamorphic grade parts of the Complex yielding the older ages. Cooling ages of 10 Ma imply that metamorphism of the Aileu Complex must have commenced by at least ~12 Ma. Metamorphism at this time is attributed to an arc setting rather than the direct result of collision of the Australian continent with the Banda Arc, an interpretation consistent with the new provenance data. Geological mapping of Ataúro, an island in the volcanic Banda Arc north of Timor, reveals a volcanic history of bi-modal subaqueous volcanism. 39Ar/40Ar geochronology of hornblende from dacitic lavas confirms that volcanism ceased by ~3 Ma. Following the cessation of volcanism, coral reef marine terraces have been uplifted to elevations of 700 m above sea level. Continuity of the terraces at constant elevations around the island reflects regional-scale uplift most likely linked to sublithospheric processes such as slab detachment. North of Timor, the near complete absence of intermediate depth seismicity beneath the inactive segment of the arc is attributed to a slab window that has opened in the collision zone and extends to 350 km below the surface. Differences in seismic moment release around this slab window indicate asymmetric rupture, propagating to the east at a much faster rate than to the west. If the lower boundary of this seismic gap signifies the original slab rupture then the slab window represents ~4 m.y. of subsequent subduction and implies that collision preceded the end of volcanism by at least 1 m.y. Variations in seismic moment release and stress state across the transition from subduction of oceanic crust to arc–continent collision in the Banda Arc are investigated using earthquake catalogues. It is shown that the slab under the western Savu Sea is unusual in that intermediate depth (70–300 km) events indicate that the slab is largely in down-dip compression at this depth range, beneath a region of the arc that has the closest spacing of volcanoes in the Sunda–Banda arc system. This unusual state of stress is attributed to subduction of a northern extension of the Scott Plateau. Present day deformation in the Savu Sea region may be analogous with the earliest stages of collision north of Timor.
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ItemStructural and thermal evolution of the Gulf Extensional Province in Baja California, Mexico: implications for Neogene rifting and opening of the Gulf of California( 2009)The Gulf of California in western Mexico is a prime example of a young passive margin that is currently undergoing the transition from continental rifting to seafloor spreading. With less than ~25 km of the width of the original continental surface area submerged, the northern Gulf Extensional Province represents a key area to assess the history of strain localisation during the early stages of continental extension. Geological mapping revealed that the basins and ranges of the Sierra San Felipe, located in the hanging wall of the Main Gulf Escarpment, are bounded to the east by an en-echelon array of left-stepping moderate- to low-angle normal faults that represent the next dominant set of normal faults from the break-away fault in direction of transport. Structural displacement estimates suggest up to ~4.5–9 km of broadly east-directed extension on the Las Cuevitas, Santa Rosa and Huatamote detachments. Fault kinematics suggest a transtensional stress regime with NE- to SE-directed extension and permutating vertical and N–S subhorizontal shortening. Clockwise vertical-axis block rotations and constrictional folding of the detachments were an integral part of the late Miocene to Pleistocene deformation history of the San Felipe fault array. This overall constrictional strain regime is indistinguishable from the present-day deformation in the Gulf Extensional Province and indicates that the fault array formed during a single phase of integrated transtensional shearing since rifting began in the late Miocene. Apatite fission track (AFT) and (U-Th)/He results of Cretaceous crystalline basement samples from the Sierra San Felipe record a three-stage Cenozoic cooling history. Moderate cooling (~4–7ºC/m.y.) during late Paleocene to Eocene times is attributed to progressive down-wearing and bevelling of the ancestral Peninsular Ranges. Beginning at ~45–35 Ma, a period of tectonic quiescence with cooling rates of ≤1ºC/m.y. marks final unroofing of the basement and the development of a regional Oligocene to Miocene peneplain. Thermal modelling of samples from the footwall of the Las Cuevitas and Santa Rosa fault systems indicates that accelerated cooling began at ~9–8 Ma. This cooling pulse is attributed to tectonic denudation of the footwall and implies that faulting initiated synchronously on both detachments at ~9–8 Ma. Late Miocene deformation occurred distributed throughout the Sierra San Felipe, but started waning after the Pacific-North America plate boundary had localised into the Gulf of California by ~4.7 Ma. During a late Pliocene structural reorganisation in the northern Gulf, the locus of extension shifted from the Tiburón to the Delfín basins, thereby initiating strike-slip faulting on the Ballenas fracture zone, a transform fault located approximately 1.5–4.5 km offshore in central Baja California. This is consistent with low-temperature thermochronometric data from two horizontal transects perpendicular to the strike of the transform, which document a pronounced late Pliocene to Pleistocene heating event that is related to the structural and/or magmatic evolution of the transform fault. During reheating, maximum paleotemperatures reached >100–120ºC near the coast, but did not exceed ~60ºC some 5–8 km further inland. Highly non-systematic overprinting patterns are best explained by circulating hydrothermal fluids, which are most likely associated with magmatic leaking along the transform fault. AFT and (U-Th)/He ages from a vertical profile collected on the Libertad escarpment, which forms part of the Main Gulf Escarpment in central Baja, pre-date Neogene extension and indicate that rift-related denudation was insufficient to expose samples from temperatures higher than the sensitivity zones of the two systems. One sample from the base of the escarpment however, records a middle to late Miocene hydrothermal overprint and suggests that extension in central Baja California likely initiated before ~10–8 Ma.
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ItemLate Neogene stratigraphy and sedimentation across the Murray Basin, southeastern Australia( 2007)The Late Neogene sedimentary sequence of the Murray Basin provides an excellent opportunity to examine paleoenvironmental change across southeastern Australia. A detailed stratigraphic analysis of sediments deposited within the basin in the last 10 Ma was undertaken to assess the influence of tectonic and eustatic processes on deposition. Stratigraphic observations and radiogenic isotope analysis reveals the onset of deposition by 7.2 Ma with a transgressive episode that deposited the marine marls of the Bookpurnong Beds. Deposition was restricted to the central and eastern parts of the basin due to the Hamley Fault. In the west, subsurface elevation contours indicate the presence of incised paleodrainage channels above Miocene limestones, which facilitated the formation of a large estuary system at 5.3 Ma. The sediments of the Norwest Bend Formation were deposited within this western region, while further east, the Loxton-Parilla Sands strandplain deposited over 214 coastal ridges. The basal parts of this unit occur as lateral equivalents to the sediments of the Lower Norwest Bend Formation (in the west). Topographic and magnetic data reveal that tectonism was active during this period and resulted in the erosion and truncation of strandlines. Tectonic evidence and an estimated minimum 28,037 year cyclicity between strandline sets, suggests that the Loxton-Parilla Sands strandlines do not represent an unbroken record of glacioeustatic change. The subaerial exposure of these sediments at approximately 3.0 Ma caused the formation of a calcareous karst above the Norwest Bend Formation and a ferruginous and/or silicious cap (the Karoonda Surface) above the Loxton-Parilla Sands. The stratigraphic position of these surfaces are indicative of a regional widespread unconformity. The Douglas-Blackburn paleodrainage system in western Victoria was dammed during the Mid-Late Pliocene by uplift associated with the Padthaway High, which caused the formation of a 400,000 km2 lacustrine system, known as Lake Bungunnia. Topographic analysis indicates that Lake Bungunnia comprised at least four distinct sub-basins with water depths of up to 30 metres, with lake shorelines indicating that active tectonism occurred during this period. The resulting lack of sediment input to the coast caused the formation of the Kanawinka Escarpment, a large erosional scarp along the southern margin of the Padthaway High. The geomorphology of the modern Murray Basin can be directly attributed to the demise of the Lake Bungunnia system. Movement along the Morgan Fault in the west at approximately 700 Ka, resulted in the draining and progressive drying of Lake Bungunnia as a breach was created along the Padthaway High. The Murray River gorge as observed today was incised following this episode. The modern Murray River (and playa lakes such as Lake Tyrell) occupy the lowest elevations along the former sub-basins of Lake Bungunnia. The Late Neogene sedimentary sequence across the Murray Basin illustrates a complex interaction of eustatic and tectonic processes on deposition. Sedimentation within strandline, estuarine and lacustrine systems, particularly in the western Murray Basin, display evidence of significant tectonic control. This highlights the important role that neotectonic processes have played in shaping southeastern Australia.
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ItemModelling of canal water acidity due to acid sulphate soils: a case study of the Camau Peninsula, Mekong Delta, Vietnam( 2008)Acid Sulphate Soils (ASS) often cause acidic pollution in canal water, which negatively impacts on water quality, biodiversity and the livelihood of farmers and fishermen, especially the landless poor. The problem is particularly acute in the coastal zones, where people already suffer from the consequences of salinity intrusion. Reducing acidic pollution is important for improving agricultural and aqua-cultural production and also the living conditions of people living in coastal zones with ASS. This study aims at developing an analytical tool that can simulate the propagation of acidic pollution and that would allow planers and managers to develop water management options and other resource management measures to reduce acidic pollution in the canal network of a coastal zone. This study utilizes a systems approach, with a series of field, laboratory studies, in combination with statistical and GIS-based analyses and simulation modelling. Field and laboratory studies were carried out during 2001 - 2006 in Ca Mau peninsula, Mekong Delta, Vietnam, to fill in knowledge gaps on the source and amount of acidic loads from soil to the water surroundings, their interaction with saline water and their propagation in the canal network. Knowledge generated from this study was used in developing and validating a model to simulate the propagation of acidity in the tidal canal network with brackish water. Measured data showed that the acidic pollution in the canal network varies seasonally. The pH of the canal water was lowest (3 – 4.5) at the beginning of the rainy season and highest (7 – 7.5) at the end of the rainy season and during the dry season. The reduced dredging activities in year 2005 and 2006 may explain why the acidic pollution decreased in 2005 – 2006 compared with 2001 –2004. The most serious acidic pollution occurs when the two following conditions are present simultaneously: (i) The existence of newly dredged canals (and hence the deposition of the excavated spoils on the canal embankment) in areas with ASS (especially with a severe ASS); and (ii) little or a lack of water exchange from tidal flows. Field experiments showed that ASS embankments within 2-3 years after dredging represent a high acidity hazard because they can release into the canal a total acidity, mainly from runoff and seepage water, of up to 2.7 mol H+day-1 per meter length of canal embankment. Functional relationships were established allowing quantification of the daily acid load transferred from fields and canal embankments to the canal network. A laboratory titration experiment showed that saline water could buffer the effects of acidic pollution in the canal water. A new ACIDITY module was developed and was coupled to an existing hydraulics and salinity model (the Vietnam River Systems And Plains - VRSAP). The model was calibrated with measured data from 2003 and validated with data from 2005. The Model is the first of its kind able to simulate the temporal and spatial dynamics of changes of pH (as an indicator of acidity) at a regional scale, together with salinity and water flow characteristics in a tidal canal network with brackish water. The Model can be used to investigate the effects of different scenarios of water and other resource management options on the extent of acidic pollution in a coastal area. Analysis of simulation runs for various scenarios indicate that opening the two main sluices along the East Sea at high tide in one day every week in May and June for saline water intake, combined with widening the canals that connect these sluices to the West Sea can eliminate the acidity problem in the study area. Large scale dredging of canals of ASS in fresh water zone should be avoided as it can create severe acidic pollution of the canal water.