School of Earth Sciences - Theses
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ItemModelling of canal water acidity due to acid sulphate soils: a case study of the Camau Peninsula, Mekong Delta, Vietnam( 2008)Acid Sulphate Soils (ASS) often cause acidic pollution in canal water, which negatively impacts on water quality, biodiversity and the livelihood of farmers and fishermen, especially the landless poor. The problem is particularly acute in the coastal zones, where people already suffer from the consequences of salinity intrusion. Reducing acidic pollution is important for improving agricultural and aqua-cultural production and also the living conditions of people living in coastal zones with ASS. This study aims at developing an analytical tool that can simulate the propagation of acidic pollution and that would allow planers and managers to develop water management options and other resource management measures to reduce acidic pollution in the canal network of a coastal zone. This study utilizes a systems approach, with a series of field, laboratory studies, in combination with statistical and GIS-based analyses and simulation modelling. Field and laboratory studies were carried out during 2001 - 2006 in Ca Mau peninsula, Mekong Delta, Vietnam, to fill in knowledge gaps on the source and amount of acidic loads from soil to the water surroundings, their interaction with saline water and their propagation in the canal network. Knowledge generated from this study was used in developing and validating a model to simulate the propagation of acidity in the tidal canal network with brackish water. Measured data showed that the acidic pollution in the canal network varies seasonally. The pH of the canal water was lowest (3 – 4.5) at the beginning of the rainy season and highest (7 – 7.5) at the end of the rainy season and during the dry season. The reduced dredging activities in year 2005 and 2006 may explain why the acidic pollution decreased in 2005 – 2006 compared with 2001 –2004. The most serious acidic pollution occurs when the two following conditions are present simultaneously: (i) The existence of newly dredged canals (and hence the deposition of the excavated spoils on the canal embankment) in areas with ASS (especially with a severe ASS); and (ii) little or a lack of water exchange from tidal flows. Field experiments showed that ASS embankments within 2-3 years after dredging represent a high acidity hazard because they can release into the canal a total acidity, mainly from runoff and seepage water, of up to 2.7 mol H+day-1 per meter length of canal embankment. Functional relationships were established allowing quantification of the daily acid load transferred from fields and canal embankments to the canal network. A laboratory titration experiment showed that saline water could buffer the effects of acidic pollution in the canal water. A new ACIDITY module was developed and was coupled to an existing hydraulics and salinity model (the Vietnam River Systems And Plains - VRSAP). The model was calibrated with measured data from 2003 and validated with data from 2005. The Model is the first of its kind able to simulate the temporal and spatial dynamics of changes of pH (as an indicator of acidity) at a regional scale, together with salinity and water flow characteristics in a tidal canal network with brackish water. The Model can be used to investigate the effects of different scenarios of water and other resource management options on the extent of acidic pollution in a coastal area. Analysis of simulation runs for various scenarios indicate that opening the two main sluices along the East Sea at high tide in one day every week in May and June for saline water intake, combined with widening the canals that connect these sluices to the West Sea can eliminate the acidity problem in the study area. Large scale dredging of canals of ASS in fresh water zone should be avoided as it can create severe acidic pollution of the canal water.