School of Earth Sciences - Theses
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ItemFire weather in two regions of the Southern Hemisphere( 2017)This thesis investigated fire weather in Victoria, Australia and the Ecuadorian Andes. The selection of these areas considered several criteria. First of all, bushfires cause significant impacts in these two regions. Victoria has endured some of the most catastrophic bushfire events in Australian history (e.g. “Black Friday” (1939), “Ash Wednesday” (1983), “Black Saturday” (2009)). On the other hand, bushfires in Ecuador destroy every year large areas of national parks in one of the most biodiverse countries in the world. Secondly, the El Niño- Southern Oscillation (ENSO) is a strong climate driver in the two study areas. Finally, Victoria and Ecuador share the Eucalyptus as the dominant bushfire-prone species. The aim of this thesis is to better understand the drivers and evolution of fire weather in these two regions of the Southern Hemisphere. Specifically, it examined three aspects. First of all, it investigated fire weather spatial patterns in Victoria and their relationship with associated events like heatwaves. Subsequently, the study explored long-term fire weather variability and changes. Finally, the investigation evaluated the influence of ENSO and other climate drivers over fire weather. The analyses used three groups of data: bushfire records, meteorological and climate indices data. Consistent bushfire records were available only for Victoria during the period 1961-2010. Additionally, the investigation required observations from weather stations in Victoria and the Ecuadorian Andes. This research also analysed reanalysis data from the Twentieth Century Reanalysis Project (20CR) and the European Reanalysis of Global Climate Observations ERA-Clim project (ERA-20C). The study had a stronger emphasis on ENSO since it affects both regions. This research used two indices to represent fire weather. The first index was the McArthur Forest Fire Danger Index (FFDI). This Australian metric was designed for an Eucalyptus environment. Therefore, this investigation applied the FFDI for Victoria and Ecuador. Additionally, this thesis proposes an alternative fire weather index for Victoria: the “Victorian Seasonal Bushfire Index” (VSBI). The VSBI combines local meteorological variables and sea surface temperature in ENSO regions to represent—and predict—extreme fire weather. The investigation of fire weather in Victoria and the Ecuadorian Andes yielded several findings. First of all, bushfire and heatwave weather patterns display differences from one another in Victoria. These comparisons used synoptic climatologies with reanalysis data during the period 1961-2010. Additionally, the investigation showed that Victoria experienced an increase in fire danger during the period 1974-2010. There is also weaker evidence suggesting an increasing trend since 1920. “El Niño” events are the leading remote driver of fire activity in Victoria. In fact, the incorporation of ENSO indicators in a simple index (VSBI) shows skill to forecast extreme fire weather in this region. For the Ecuadorian Andes, this research indicates that its fire danger season (July-September) is longer than reported. October and November also display “high” fire danger during the period 1997-2012. Finally, “El Niño” events increase fire risk in the Ecuadorian Andes.
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ItemMeasurement and modelling of heat flow in the Gippsland Basin, Victoria( 2015)Geothermal energy has the potential to provide significant quantities of highly available power with little environmental impact. Enhanced geothermal system (EGS) technologies have the potential to become major contributors to global energy production, with a much wider geographic scope than the more established conventional geothermal systems. Certain favourable geological conditions have been recognised as providing improved prospectivity for EGS resources, primarily elevated heat flow rates and thermally insulating cover sequences. Most attention has been given to the location of regions having anomalously high heat flow, typically due to increased heat production in basement rocks such as granites rich in radiogenic isotopes. Little attention has been paid to extremes in thermal insulation, which offer an alternative but equally effective mechanism for increasing geothermal gradients and thus reducing the depth to a geothermal resource. Large and thick deposits of highly insulating coal present a unique thermal environment, where the commonly assumed one-dimensional relationship between surface heat flow and temperature at depth described by Fourier's Law is not maintained due to heat refraction -- a three-dimensional process. Understanding the effects of heat refraction due to thermal insulation and its effect on surface heat flow is a crucial element of exploration strategies in coal-bearing sedimentary basins. The onshore Gippsland Basin, and in particular the Latrobe Valley, is an ideal setting to study the effects of buried confined insulators on surface heat flow and thermal structure. This thesis combines the results of observational insights from empirical field data collection with mathematically driven insights of theoretical models, and simulation-driven insights of numerical finite-element modelling. Additionally, it explores the relatively modern paradigm of data-driven statistical science to generate predictions of rock properties from related intrinsic variables. Measured surface heat flow is moderately variable, with the ten most reliable calculations from borehole data having an interquartile range of 61--78 mW/m², with a mean and standard deviation of 72±14 mW/m², slightly higher than previous estimates. Groundwater advection identified in previous studies appears to affect the thermal structure of only the Cainozoic stratigraphy. Losses of up to 37 mW/m² in the vertical heat flow in the sandy Balook Formation of borehole Rosedale-301 represents a local maximum of heat transfer associated with groundwater advection. Only minor thermal effects are observed in the uppermost Mesozoic section, indicating a return to a dominantly conductive thermal regime there. The self-organising map technique was applied to the prediction of lithostratigraphy and thermal conductivity from well-log data. It successfully identified 91.3% of lithostratigraphy samples from a supervised mapping of well-log data. Mapping of thermal conductivity with corresponding well-log data produced more variable results compared with a petrophysical log interpretation technique over a large cohort of boreholes. However, the SOM analysis returned predicted values with a better correlation with measured values at sampled depths, required less pre-processing of log data, and was able to perform with non-standard log data and legacy tools. With further refinements of the technique, potential improvements may be made with its prediction performance of thermal conductivity and other rock properties. Heat flow theory applied to an idealised simulation of the Latrobe Valley coal seams showed that temperature increases of 35°C beneath the coal are possible over a reference model having no such insulation. Finite-element forward models of cross-sections and 3D volumes through the onshore Gippsland Basin identified highly variable surface heat flow, having up to ±30 mW/m² variance from the basal flux input. Complex patterns resulting from heat refraction were produced, with two common features indicative of confined insulators: 1. the greatest increase in subsurface temperature is correlated with the greatest decrease in surface heat flow, however, 2. surface heat flow tends to be slightly increased above the margins of buried insulators. The main implication from these results is the identification of an end-member insulation-dominated geothermal resource style, requiring new strategies for exploration and resource targeting.
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ItemThe hydrogeology of the Gippsland Basin, and its role in the genesis and accumulation of petroleum( 2002)The Gippsland Basin of southeastern Australia is the most energy-rich basin of Australia producing petroleum, gas and brown coal. Three-quarters of the Basin lies offshore and the rest onshore. The basin was initiated as a rift valley, caused by the separation of the Australian continent from the Antarctic followed by a number of tectonic events throughout the basin history. Early Cretaceous sedimentary rocks form the basement, which is in turn covered with Late Cretaceous to Recent sediment of sand, clay, limestone, and brown coal seams. The total thickness of the in-filling sediments offshore attains up to 6000 m, but onshore is up to 1200 m. There are three main acquifer systems, the Hydrostratigraphic Units 2, 4, and 7, all of which are confined. The two lower aquifer systems, Units 4 and 7, contain high temperature groundwater. It is generally agreed that the hydrocarbons offshore have been derived from terrestrial matters including brown coal and ligneous clay offshore. In the present study, the author has developed a case that hydrocarbons offshore being derived not only from the offshore source but also from onshore brown coals and coaly matter and in this hydrocarbon forming processes, groundwater has played a significant role. The Central Deep, in particular, provides favourable conditions for hydrocarbon maturation. Throughout the basin history, the Central Deep has experienced the oil window temperatures. In supporting this hypothesis, geochemical studies on groundwater, brown coal, and hydrocarbons as well as hydrodynamics are presented.
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ItemThe Permian glacial sediments of central Victoria and the Murray Basin: their sedimentology and geochemistry( 1986)This study investigates the sedimentology and geochemistry of Permian glacial sediments cropping out in the Bacchus Marsh and Derrinal areas in central Victoria and in the subsurface beneath the Cainozoic Murray Basin in Victoria, New South Wales and South Australia. Facies analysis of the Bacchus Marsh Formation, based on a critical review of literature on glacial sedimentary processes and environments, identifies the following major facies groups: 1. Subglacial tillites deposited beneath wet-based ice. Some of these tillites exhibit structures indicative of a number of subglacial processes such as frictional lodgement of large clasts, subglacial bed deformation, subglacial meltwater flow and subglacial size sorting of clasts. Other subglacial tillites are essentially structureless. 2. Bedded diamictites to sandstones deposited predominantly by ice-rafting of debris into standing water. 3. Fluvial outwash sandstone and conglomerate facies that are finer-grained than typical proglacial outwash facies. 4. Deltas and subaqueous outwash fans vary from sandy sediments deposited by proglacial and subglacial streams to coarse, poorly sorted complexes deposited as debris aprons close to the ice front. Abundant underflow deposits suggest that less than normal marine salinities prevailed in these water bodies, even if they were arms of the sea. 5. Supraglacial tillites consisting of sandy diamictites to pebble conglomerates. Facies in the thickest sequence in the Bacchus Marsh area suggests that the area was covered by a major ice mass at least 8 times. Minor glacial advances took place during predominantly ice-free periods. The Derrinal Formation consists of a basal unit of predominantly subglacial tillite deposited in shallow glacially excavated valleys overlain by a complex of subglacial and supraglacial facies deposited by about 8 minor advances of a small ice tongue. Facies relationships in this part of the sequence are confused by intense deformation of the sediment pile during the melting of buried ice and dewatering of saturated diamictons. A major ice advance then overwhelmed the area depositing thick subglacial tillite. The Urana Formation, beneath the Murray Basin, is dominated by marine ice-rafted diamictite and mudstone. Rhythmically bedded siltstone and claystone, sediment gravity-flow deposits, traction-current deposits, and, possibly, subglacial tillites are also present. Facies assemblages in some drill holes indicate areas that were never covered by grounded glacial ice. Sedimentological and palaeontological evidence suggests that the Urana Formation was deposited towards the end of the glaciation. Ice motion indicators and ice sheet limits inferred from the facies assemblages in the Urana Formation are used to estimate the thickness of the ice over central Victoria during glacial maxima. These estimates support the conclusion drawn from the facies analysis that the ice was a large ice sheet. Comparisons of ice movement directions for central Victoria and formerly adjacent parts of Gondwana suggest that a large ice sheet was centred in North Victorialand. Major and some trace elements analyses of the clay component of marine and non-marine diamictites were used to test a number of methods of distinguishing marine from nonmarine glacial diamictites. None of the methods were clearly successful because sediment detrital mineralogy dominates the geochemical composition though V/Cr ratios may be useful in some circumstances.
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ItemTransport, attenuation, and degradation of organic chemicals in a basaltic aquifer system near Melbourne, Australia( 1996)Groundwater in the Pliocene to Pleistocene fractured and jointed Newer Volcanics basaltic aquifer system beneath Melbourne's industrialised western suburbs is extensively contaminated by a wide variety of organic and inorganic compounds. Groundwater in Tertiary sediments underlying the Newer Volcanics is probably also contaminated by the same sources. The main objectives of this research were 1) to assess the types, concentrations, and distribution of contaminants in the Newer Volcanics aquifer system in Melbourne's western suburbs and at a selected contaminated site and 2) to determine contaminant transport, attenuation, and degradation processes affecting organic contaminants in this aquifer system. Contaminants detected in the Newer Volcanics aquifer system during this research include phenols, volatile organic compounds, polynuclear aromatic hydrocarbons, polychlorinated biphenyls, metals, and inorganic anions. The groundwater flow system in the study area comprises a single heterogeneous and anisotropic unconfined aquifer, and includes both the Newer Volcanics and underlying sedimentary units (the Brighton Group and the Werribee Formation), although hydraulic connection of these units to the volcanics is irregular. Groundwater flow in the Newer Volcanics is through vesicular and/or scoriaceous lava flow tops and bottoms, in intercalated fluvial deposits, and through the fractured and jointed lava flows. Locally (scale of less than I km square), the basaltic aquifer system may consist of hydraulically separated shallow and deep aquifer zones that are connected on a larger scale. The deep aquifer zones may be semi-confined to confined. Groundwater in the study area is recharged via throughflow from upgradient and infiltration of rainfall. Discharge from the Newer Volcanics in the study area is primarily to underlying sedimentary formations, but also to surface water features and directly to Port Phillip Bay. Several mechanisms which reduce contaminant concentrations are possible in the Newer Volcanics aquifer system. These include volatilisation, dispersion and diffusion, transient storage, matrix diffusion, sorption, hydrolysis, and biodegradation. However, the nature of porosity in the Newer Volcanics may significantly extend the lifetime of contaminant plumes via the processes of transient storage and matrix diffusion. The primary mechanisms of attenuation and degradation of organic contaminants in the Newer Volcanics aquifer system are probably biodegradation, matrix diffusion, sorption, and dispersion (for non-reactive contaminants) in order of decreasing effect. Biodegradation at the water table and discharge areas will also be significant because of atmospheric contact and increased dissolved oxygen concentrations. Because of the relative lack of organic carbon in the basaltic aquifer system, sorption will occur mainly to mineral surfaces in clay-rich zones and within the rock matrix (concurrent with matrix diffusion). In some cases, relatively undiluted contaminants may be transported along preferred flow paths to discharge locations where they may pose a potential threat to the environment prior to degradation or attenuation. It was found, at least with phenols and volatile organic compounds in groundwater at a study site, that contaminants are degraded and/or attenuated rapidly, probably via biodegradation, matrix diffusion, and sorption. Biodegradation testing of groundwater at this study site confirmed the existence of microorganisms in the aquifer system capable of aerobic degradation; indirect evidence may indicate the presence of anaerobes.
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ItemStructural analysis of selected duplex soils( 1971)The profile characteristics, geographical extent and general environmental relationships of duplex soils are described. They are shown to be an important group in Australia and particularly in Victoria. The variety of approaches and definitions employed by investigators of soil structure are discussed. These are contrasted with the definition used in this thesis which incorporates the concepts of spatial distribution and orientation of vectorial fabric elements in the soil. The importance of describing structural features at a number of scales is emphasized. At each scale an attempt is made to quantitatively describe (where possible) the three or two-dimensional geometrical properties of the soil components. A structural classification of duplex soils that incorporates a number of descriptive geometrical elements is proposed. A detailed study is made of the structure and related chemical, physical and mineralogical properties at an undisturbed site (Boorook) in Western Victoria. The ground surface at the Boorook site is described as being deformed into gilgai microrelief. It is demonstrated that soil structural analysis can be usefully employed to develop a swelling mechanism that explains how the Boorook gilgai probably formed. The data and subsequent analysis tends to place some doubt on mechanisms proposed by past workers. A detailed study is also reported from a site (Hartwell) near Melbourne. The site is described as being illustrative of profiles that show little or no internal and ground surface deformation. An unfolded stoneline is considered to be the principal structural feature. The mechanism for the formation of the stoneline is shown to probably involve gravitational settling of the grains in a fluid-like medium. Regional investigations of profiles throughout Western and Central Victoria and New Guinea are also described. It has been found that the principles and techniques of soil structural analysis can also be applied to buried soil structures. By these means it has been possible to establish that buried fold-like structures seen in section in a road cutting at Terang, are in fact relics of gilgai. Experimental models have assisted the investigations into the structure of duplex soils and have provided additional information on the dynamic interaction of moisture with the soil components. The main processes and sequences in the genetic development of structure of duplex soils as discussed in the light of observations of natural structures and experimental results. Attention is drawn to the differences between the dominant structural processes in the two main horizons of the profile. The approach of soil structural analysis is formalized for profile studies into the discipline of Structural Pedology. The principles of Structural Pedology threaded through the body of the thesis are summarized and shown to be very similar to those of Rock Fabric Analysis. The need for an interdisciplinary approach in this field is emphasized. It is shown that soil structural analysis is not limited to Pedology but rather can be applied to a number of academic and applied problems in a variety of disciplines that include Engineering (Soil Mechanics), Earth Sciences, Agriculture, Soil Erosion and Conservation.
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ItemThe geology, petrology and geochemistry of the Otway formation volcanogenic sediments( 1983)The geology, petrology and geochemistry of the Early Cretaceous Otway Formation have been investigated in detail and used to determ ine the nature of the source rocks and to develop a model for the diagenetic and low-grade metamorphic readjustments. The fluviatile Otway Formation was deposited in continental rift grabens that stretched some 1000 km along the southern coast of Australia during the Early Cretaceous. The main areas of deposition in the Otway, Gippsland and Bass Basins contain an estimated 100,000 cubic kilometres of detritus. The major part of this detritus was derived from pyroclastic material which has been shown by the fission track dating studies to have been derived from contemporaneous volcanism. The pile of volcanogenic material comprising the Otway Formation is at least 3 to 4 km thick in the main basins. The sediments are entirely non-marine and were deposited by large scale multichannel streams cut in extensive floodplains. The streams deposited thick multistorey channel sandstones in sheet-like bodies and a diverse spectrum of overbank mudstones and fine-grained sandstones. The complex channel sandstones fine upwards but have numerous erosional breaks indicating repeated flood cycles. Whereas the channel deposits have internal features consistent with braided stream channels the overall system has a large proportion of floodplain which was been considered in the past to have been a feature of meandering channels. The oversupply of volcanogenic detritus is considered to have been responsible for the development of the multiple channel depositional system in a climate of high seasonal rainfall. Whole rock chemical analyses of all lithologies in the sedimentary suite, recalculated i.nto a set of normative minerals, have proved useful in the distinction and description of sedimentary rocks in general. P20S was found to be useful for the identification of Early Cretaceous soil forming processes. The study of the chemical composition of detrital minerals has demonstrated the usefulness of this approach in the identification of the nature of the source magmas of volcanogenic sediments. For the Otway Formation, analyses of clinopyroxenes, amphiboles, feldspars and sphene in particular, have shown that high potassium dacitic to shoshonitic volcanism dominated during Early Cretaceous rifting. The new data on the geology and mineralogical and chemical features of the Otway Formation have application to the study of diagenesis and low-grade metamorphism in volcanogenic sediments in general. (From Abstract)
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ItemTectonic geomorphology of the Bogong and Dargo High Plains region, east Victorian highlands, Australia( 1999)The Australian Alps, a sub-region of the Australian Eastern Highlands, have enigmatically high elevations of relief for a highland belt renowned for its ancient origins and landscapes. In debates over the Eastern Highlands history, the development and significance of the Alps have been under-represented. This study defines the morphological extent of the Australian Alps and investigates their tectonic and erosional development. The focus of investigation is the Bogong and Dargo High Plains area and the broader surrounding highlands region. The Cainozoic history of this area has not been investigated in detail since last century. The geological record of the region has substantial gaps, and the erosional history is the main indicator of tectonic change. A methodological structure different to traditional approaches is devised for this study. Cause and response are compared on a process geomorphology basis. Causes investigated are (1) intra-highland tectonics and (2) basin tectonics and sea level change. Denudational relief change is the main response investigated. Spinal and temporal comparison of quantitative results enables relationships to be determined. Peak height distribution and relief observations are used to define the morphological context of the Australian Alps. Within the Alps, the high plains area is used as a case study. Tectonic constructional morphology is investigated using peak height distributions, lineament analysis, tectonic landforms and lava offsets. A Cainozoic fault block is identified, and reactivated fault displacements are determined for bounding and intra-block faults. The erosional development of the area is determined and compared with the constructional morphology results. The sub-volcanic relief of the Bogong Volcanic Province is mapped and compared with post-volcanic stream incision. Guidelines are established for interpreting strath terraces and strath terrace long profiles are used to reconstruct the post-volcanic stream erosion development. Sources and magnitudes of oversteepened stream reaches in the present rivers are identified. Spatial and temporal relationships between fault reactivation and stream incision are determined, and the relative roles of active and passive tectonics are assessed. The tectonic and erosional development of the fault block is reconstructed in cross-sectional form. Finally, the proportion and nature of highland margin-derived stream incision is identified. This study finds that the Australian Alps were substantially affected by fault block uplift during Oligocene, with more minor phases in the Miocene and Pliocene. Broader highland margin warping accompanied fault block uplift. Uplift amounts varied between 150m and over 1000m according to proximity to major faults. Stream incision was upstream-increasing and periodic, with three incision phases during the Oligocene and Pliocene. The later phases include a possible isostatic rebound component. An additional incision phase unrelated to uplift occurred in the Gippsland Basin catchment during the Quaternary. The Australian Alps is delineated here as a separate entity within the Eastern Highlands, with its own tectonic history. Cainozoic uplift created the higher elevations and greater relief of the Alps. This history is not representative of the Eastern Highlands generally, and it should not be used as a guide to a ‘united’ Eastern Highlands uplift. The highlands consist of a ‘patchwork’ of landscape evolution scenarios, rather than a single tectonic province. More definable tectonic histories can be derived from erosional regions of geologically unrecorded time using a process geomorphology perspective. This study provides a suggested step towards redressing interpretation problems recognised in landscape evolution studies generally.
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ItemThe geology and petrology of the Lower Devonian Buchan Group, Victoria( 1981)This study is devoted to a detailed examination of the stratigraphy and petrology of the late Lower Devonian (Emisan) Buchan Group, an essentially carbonate sequence. The Buchan Group begins with the lenticular Spring Creek member of the Buchan Caves Limestone. This consists of terrigenous clastic sediments derived from erosion of the underlying Snowy River Rhyodacites. Lithologies range from conglomerates and breccias with rhyodacite pebbles, through arkosic sandstones to quartz sandstones and shales. Pyroclastics, previously identified in this unit, are absent. The Spring Creek member changed from non-marine to marine as the main transgression became established and was followed by a change to carbonate deposition.
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ItemPhysical and chemical hydrogeology of the Otway Basin, southeast Australia( 2009)The Otway Basin of southeast Australia is the subject of this thesis, which incorporates pre-existing geological, hydraulic and major element hydrogeological data with new isotope hydrogeochemical investigations. The region is an Upper Cretaceous–Tertiary basin, filled with siliciclastic and calcareous aquifers and aquitards and characterised by late volcanic activity, pervasive faulting and karstification. (For complete abstract open document.) As part of this study, an hydrogeological database is compiled for the Otway Basin region from existing distinct datasets from the states of Victoria and South Australia. Utilising this new resource, the data are reinterpreted into a 3D model of the hydrostratigraphy for the basin in GoCAD, and interpolated surfaces of hydraulic head and electrical conductivity are created for 5 aquifers/aquitards. The Victorian hydraulic head data is analysed for long term declining or inclining trends and hydrograph trend maps are created for different aquifer systems. The data are also compiled into representative cross sections of flow and chemical composition, with one section located in each of the three major sub-basins. The records of groundwater chemistry from the Victorian section of the Otway Basin are used to plot the relative concentration of major cations and anions for the main aquifers. More than 120 groundwater samples were taken for analysis of major and minor ion concentration and/or oxygen, hydrogen, carbon, strontium and chlorine isotope composition. These data are used to characterise the hydrogeochemical evolution of the groundwater and to identify the processes that the groundwater drives or experiences in the system. The potentiometric maps and cross sections reveal the interconnected nature of the flow in all aquifers and the relationship between local and regional flow systems. Regional flow paths originate inland near basement highs or the basin margins. In the shallower aquifers they terminate at the coastline where the groundwater mixes with ocean water at a diffuse interface and density differences induce groundwater discharge at the land surface or the ocean floor. In the deeper confined aquifers, discharge is submarine via several possible mechanisms, which include: diffuse intergranular leakage to overlying units; flow along faults or volcanic conduits; and/or seepage directly to the ocean from exposed sections of the aquifer, e.g. in submarine canyons. These mechanisms may be operating up to 50 km offshore but the interface is currently migrating landward, which will result in a shortening of that estimated distance. Local-scale flow lines are complex and may be oriented against the direction of regional coastward flow. Local hydraulic divides are often associated with volcanic eruption centres, which have elevated topography and relatively high hydraulic head, making them important recharge zones. These zones contain low salinity groundwater because infiltration is relatively rapid. Conversely, basalt flows that have developed clay horizons through weathering reduce drainage and allow significant evapotranspiration which concentrates the cyclic salts in solution. Many local flow systems discharge mainly via evapotranspiration, which acts again to concentrate the cyclic salts in solution. Other local discharge zones are rivers, creeks and lakes or lagoons that receive baseflow and seeps and springs associated with geological contacts or boundaries and faults. Evaporitic concentration of solutes in surface water bodies and shallow groundwater affects the quality of water recharging the underlying aquifers and aquitards. This quality has changed over the last 50,000 years or so due to fluctuations in climate and hence variation of the precipitation/evaporation ratio. Stresses on the aquifers are climate fluctuations, sea level change, land use change and groundwater extraction. These stresses have resulted in the system being out of hydraulic equilibrium in many cases. Lags in response to these changes in boundary conditions are identified and/or hypothesised. In particular, the confined aquifer’s response to sea level change could be subject to a lag in the order of millennia. The stress on an aquifer is often transferred to its adjacent units, in some cases inducing cross-formational leakage, which is possibly supported by radiocarbon dating evidence. The area of the Otway Ranges appears to have escaped the effects of stress to date because of its stable microclimate, its distance from the ocean and from groundwater extraction. Increase in demand on groundwater resources, development of geothermal, sequestration and hydrocarbon industries and future climate change may yet have a detrimental effect on the groundwater of the Otway Basin. Isotopic composition of the groundwater confirms its meteoric origin and chlorine isotopes from several samples of the deep groundwater indicate that accumulation of solutes along the flow path is not due to diffusion or dissolution of connate salt. Thus, the salinity of the water is sourced from cyclic salts and solutes from water-rock interaction, both of which may be concentrated by evapotranspiration. Water-rock interaction is dominated by dissolution of carbonates and weathering of silicates as a result of the surficial geology being dominated by calcarenite or limestone and young basalt. The volcanic activity has produced gas that has interacted with the groundwater, and continues to do so, fractionating oxygen, hydrogen and carbon isotopes and contributing fluorine, boron and sulphur to solution. The addition of volcanic CO2 creates an uncommon situation for water-rock interaction, where continued dissolution of carbonate and silicate minerals along the deeper flow paths is demonstrated by the silicon/chloride ratios and strontium isotopic composition of the groundwater. These water-rock interaction processes, with the addition of cation exchange, are responsible for the development of a relatively fresh Na+HCO− 3 type water that is characteristic in parts of the deep aquifer. The study confirms the existing hydrogeological understanding of the Otway Basin and forms new conclusions regarding the history of the groundwater and the processes of flow and chemical evolution by integrating numerous lines of evidence. Significant contributions of this work which improve current scientific knowledge include these findings: the maps and cross sections of hydraulic head and electrical conductivity reveal the connected nature of flow systems within all the aquifers and aquitards; geological features can induce discharge, e.g. at contacts or faults, and recharge, e.g. volcanic eruption centres; the changes to the surface drainage system as a result of the eruption of basalt flows have affected the water chemistry and flow systems in all the underlying units; there is a lag in aquifers’ responses to sea level change and therefore future migration of the interface is expected regardless of further boundary changes; climate change has influenced surface water quality by changing the regional water balance, and therefore has affected groundwater quality; the discharge from the confined aquifer is submarine via various pathways, interaction between the groundwater and volcanic gas has occurred in the past and is ongoing, and consequently mineral dissolution persists at deep levels; the origin of high salinity of brackish groundwater in all Tertiary aquifers and aquitards is concentrated solutes from water rock interaction and cyclic deposition.