School of Earth Sciences - Theses
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ItemThe geology and geochemistry of the Agnew Intrusion: implications for the petrogenesis of early Huronian mafic igneous rocks in Central Ontario, Canada( 1996-07)The Early Proterozoic Agnew Intrusion is a well-preserved leucogabbronoritic to gabbronoritic layered intrusion that is a member of the East Bull Lake suite of layered intrusions (ca. 2490-2470 Ma) occurring in central Ontario. These intrusions are related to the development of the Huronian Rift Zone, which may be part of a much more widespread rifting event that involved the Fennoscandian Shield. Structural data suggest that these intrusions have been subjected to ductile deformation and are erosional remnants of one or more sill-like bodies originally emplaced along the contact between Archaean granitic rocks of the Superior Province and an Early Proterozoic Huronian continental flood basalt sequence in the Southern Province.
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ItemGeology and tectonothermal history of The Fishery Bay Region, Eyre Peninsula, South Australia( 1998)The Fishery Bay region, southern Eyre Peninsula, South Australia, consists of Archaean charnockitic and paragneissic sequences of the Sleaford Complex intruded by Palaeoproterozoic granitoids and two generations of mafic dykes. These rocks preserve the deformational and metamorphic effects of the Kimban Orogeny and the later Wartakan Event. Within the Fishery Bay area, five separate ductile deformation events (D1-D5) are recognised, the dominant of which (D2-D3) are associated with granulite facies metamorphism. The effects of the D3 event are pervasive throughout the Fishery Bay region, with D1 and D2 preserved only in regions of low-D3 strain. The overprinting nature or D3 is recognised in the reorientation of D2 structures. The dominant response of the area to D3 strain is a series of westerly-dipping dextral oblique reverse shears with west block-up movement. Much of the strain is localised within the paragneisses and along the margins of mafic dykes recognised in the development of a NNE-trending D3 high-strain zone termed the Cape Wiles Shear Zone. D3 observations from the Fishery Bay region correlate well with previous studies conducted on southern Eyre Peninsula which lead to the inference that D3 west block-up exhumation is responsible for the positive pressure gradient that exists from west to east across the Kalinjala Shear Zone. The pressure-temperature conditions preserved in the mineral assemblages of the paragneiss units and mafic dykes record two granulite facies metamorphic events, M2 and M3. Mineral assemblages associated with M2 and M3 are similar and passage from M2 to M3 did not result in reaction textures which indicates the proximity of the thermal conditions of these two metamorphic events. M2 corresponds to the second deformational event (D2) where peak metamorphic conditions reached pressures of 8.6±3.2 kbar at 750-900°C, The second thermobaric event correlates with the third deformation event (D3) and a metamorphic peak of 4.1±1.9 kbar at 750-850°C. The decompression of the Fishery Bay region during D3/M3 is synchronous with crustal thickening of the terrain east of the area.
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ItemAustralian lineament tectonics: with an emphasis on northwestern Australia( 1994-08)Australia is transected by a network of systematic continental-scale lineaments that are considered to be zones of concentrated, aligned tectonic activity which have apparent continuity over vast distances. The influence of lineaments on the rock record can be identified in many types of data-sets, and existing data reveals previously undescribed basement influences. Several continental-scale lineaments can be traced offshore with apparent continuity for hundreds to thousands of kilometres, two of which are seen to cross the Tasman Sea in offshore eastern Australia. Geological and chronological evidence demonstrates that many of the lineaments have been zones of reactivation since at least the Early Proterozoic (- 1880 Ma) and that they appear to cross major terrane boundaries. Alternative models for their origin are a) a pre-existing lineament network maintained in an ancient basement underlying the entire continent; b) lateral propagation of crustal-scale structures; c) alignment of genetically unrelated lineaments giving the appearance of continuity. Australian deep-seismic profiles show that continental-scale lineaments are zones of crustal-scale structure which in some cases transect the crust-mantle boundary. Lineaments demonstrate many faulting styles, e.g. listric extensional (G3), planar moderate-angle thrusts (G2 l), and sub-vertical thrusts (G 17). In some cases the structural style varies laterally along the length of the lineament. (For complete abstract open document)
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ItemDeformation and the thermobaric history of the eastern coast of Williams Island( 1997)Williams Island is located off the southern coast of the Eyre Peninsula of South Australia where the Palaeoproterozoic rocks of the Lincoln Batholith intrude a portion of an Archaean basement complex. The structures of the eastern coast of Williams Island are controlled by the rheological contrast between the mafic dykes and the felsic granite gneisses that comprise the batholith. Planes of rheological weakness exist at the dyke margins along which strain is localised. The plane of failure and the kinematics along it depends upon the orientation of the dyke with respect to the stress field. Displacements at cross-cutting dyke margins indicates the occurrence of three significant deformation events, D 1, D2 and D3. By comparison, the D1 is localised to a region of outcropping Jussieu Dykes, the D2 is pervasive and the D3 is confined to the discrete Northern and Southern Shear Zones. Associated with the latter two deformations is an increase in temperature and strain rate which controls the relative strength of the metabasic and the granite gneiss rocks. Brittle extensional structures, such as boudinage, form when the mafic dykes behave in a more competent manner relative to the host, whereas ductile extensional features, like pinch and swell, infer a greater homogeneity between the rock types. The rheological contrast is inverted with a preferential increase in strain resulting in granite boudinage. The D2 fabrics arc predominantly defined by a granulite two-pyroxene assemblage and the structural elements of D3 are characterised by minerals associated with amphibolisation. Average pressure calculations of representative assemblages give 7 ± 1 kbar for M2/D2 and 12 ± 2 kbar for M3/D3, which suggests crustal thickening over D2 - D3 time. Exhumation of the crustal block therefore occurred after peak D3.
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ItemGeochemistry and mineralisation of primary and secondary platinum-group elements in the ultramafic "Alaskan-type" Owendale complex and laterites in the Fifield Region, New South Wales, Australia( 1995)The Owendale Complex belongs to a family of ultramafic-mafic intrusions that is characterised by a zonal, nonstratiform arrangement of the principal ultramafic units. The ultramafic rocks of the Owendale Complex are virtually identical to many of the Alaskan-type intrusions, however the associated gabbroic rocks (wehrlites) are K-rich and Si-undersaturated, in contrast to the tholeiitic gabbroic rocks of the Alaskan examples. The intrusion history of the Owendale Complex is thought to have involved emplacement of a gabbroic intrusion that was invaded by an ultrabasic magma, possibly while the former was still only partly solidified. Emplacement of both magmas probably occurred during Late Devonian tectonism and deformation synchronous with emplacement and crystallisation is necessary to explain the present non-stratiform arrangement of the rock units. The most obvious linkage factor between the two proposed parent magmas (gabbroic and ultrabasic) of the Owendale suites is their mutual affinity with tholeiitic basalt magmas and the similarities of their products with intrusions of alkalic basalt derivation. This suggests the possibility that the Owendale Complex rocks and those of other tholeiitic intrusions of the regions are comagmatic products of an ancestral magma that may have also produced the widespread assemblage of complexes. Viewed from this perspective, the ultramafic rocks of Owendale Complex would thus represent a very minor product of a period of regional magmatic activity. Most alloys, erlichmanite, cooperite and some grains with exclusion texture of Pt-Os-Ir-Pd-Rh are considered to represent a primary high-temperature paragenesis. Concentration of PGE in pegmatoidal units of dunite-wehrlite is explained by the accumulation of platinum-rich alloys that segregated directly from the melt at an early stage in the evolution of the complex. The high-temperature PGM segregate directly from a silicate melt and were not generated by exsolution from spinels or magmatic sulphides. These suggest that fS2 was generally low (subordinate sulphide formation) and, after some influence at the beginning, has given way to rising fO2 (chromite, olivine and Pt-Fe-Cu-Ni alloys formation). After lithification, the ultramafic rocks become subject to "reducing" conditions, i.e., conditions of lower O2 and S2 activities. Ni-Fe alloys, native Fe and Bi formed in cracks which filled the serpentine matrixes. The former PGM (erlichmanite, cooperite and Pt-Fe alloys) were exposed to the reducing conditions via cracks were desulphurated to form porous cooperite with Pt-Fe alloys and multiphase textural Os-Ir-Ni, Pt-Ir aggregates. It is plausible that the veinlets and aggregates of unnamed Rh-Sb-S, (Pt, Ir)2(Fc, Cu)3(S, Sb, AS)3 in the dunites may also have been formed by reduction of Ni-rich sulphides and erlichmanite, Pt-Fe alloys or cooperite. Late PGM are dominated by sperrylite-geversite solid solution resulting from the reaction of early PGM with a fluid phase. A hydrothermal origin is also indicated for native Fe, native Bi and awaruite (NiFe) and the base-metal sulphides (pentlandite, chalcopyrite, sphalerite, arsenopyrite, pyrite, pyrrhotite, and some Ni-Co-Fe sulfide). The cause of the reducing conditions may have been related to H2 production accompanying hydrous alteration of the dunites and clinopyroxenites. The laterites overlying the ultramafic complexes in the Fifield region are exceptionally well-developed and well-preserved weathering profiles. Field, textural and geochemical data all support a chemical weathering origin for the profiles and compatible with meteoric and ground water origins. Meteoric water with intermediate Eh and pH and negligible dissolved species sinks into the laterite where these parameters are modified. The Eh rises and pH decreases to the conditions typical of lateritic soils and the concentration of dissolved species increases. In this state the water is able to take PGE and Au into solution from a finely disseminated form in the bedrock as a part of the process of lateritisation. When the soil solution transports the PGE and Au towards a transitional interface must exist between the ferruginous and saprolite zones with lower Eh, neutral pH and lower concentration of dissolved salts. At this transitional region, deposition of the PGE and Au occurred. The presence of magnetic Pt-Fe-Cu-Ni alloys suggests that hydrothermal solutions play a later role in the Fifield region, and the alloys have grown in situ in a lateritic soil by a process involving laterite water solution in the high Eh, low pH conditions prevalent in such soil, followed by deposition when the conditions become less extreme. Some examples of the Pt-Fe alloys from such an environment become frequently strongly magnetic with larger size. It is assumed that the temperature of the hydrothermal solution is in the range of 300° - 500° C (Bowles, 1990). PGE mineralisation in the primary rocks and laterite in this region has demonstrated a good example of multi-stage process mineralisation including primary high temperature magmatic formation; low temperature postmagmatic hydrothermal alteration and residual lateritic enrichment.
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ItemMobility of base metals through regolith, Broken Hill, N.S.W.( 1993)Regolith profiles over and around zones of Pb-Zn mineralisation were investigated at Maybell and Stirling Vale, located in the Broken Hill region, N.S.W. Metasediments and metavolcanics of the Proterozoic Willyama Supergroup crop out in the study areas, with quartz-gahnite horizons hosting mineralisation. Desert loam soils in the study areas have a transported origin. Locally transported sheetwash deposits overlie a relict aeolian deposit which sits on relatively fresh Proterozoic bedrock. Mineralogy of the regolith profile is consistent with depth and landscape position. Quartz-gahnite horizons form topographic highs in both areas, containing up to 13.5% Zn. Gossanous material is associated with the quartz-gahnite rocks. No base metal containing secondary minerals were present in this weathered material but there were high proportions of iron oxides containing substantial amounts of base metals. Surrounding soils were anomalous in Zn, Cu and their pathfinders Cd and As, which outlines a mobilisation of base metals. Similar anomalies were expressed in stream sediments. Calcrete in the area, contained no anomalous levels of Zn, due to the low solubility of Zn at high pH. The majority of base metals in soils were associated with amorphous iron oxides and silicates (presumably gahnites). These metal bonding sites indicate, dispersion haloes in the regolith are due to a combination of physical and chemical dispersion. In this example of transported regolith profiles in an arid terrain, Zn and Cu are both physically and hydromorphically dispersed from weathering quartz-gahnite horizons.
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ItemGeology of the lookout area, Eyre Peninsula, South Australia( 1996)The Lookout Area, southern Eyre Peninsula, South Australia forms part of the Lincoln Batholith with outcropping Donington Granitoid Suite units of Palaeo-Proterozoic age (l840-1800Ma) and both syn-plutonic and intrusive mafic dykes. The area was surveyed and mapped at 1:500 to produce a detailed geological map including the form surface trend of structural features. The units, incorporating felsic, intermediate and mafic gneisses intruded by the mafic dyke sequences, preserve high strain mylonitic deformational features with well developed fabrics in the felsic units. The Mafic dykes are boudinaged and display asymmetries attributed to antithetic back-rotation due to extensional shear. Kinematic indicators including shear band formation, parasitic folding and strain shadows suggest a kinematic history of initial sinistral deformation post-dated by dextral west-up oblique shear associated with the formation of the principal foliation. This is in turn post-dated by local sinistral shearing. The strain associated with the deformation can be measured by use of porphyroclast shape and distribution. These results indicate that the strain is locally variable, from constrictional to flattening, but generally constrictional with an extensional ratio of approximately 6:1. The metamorphic conditions preserved by the mineral assemblages analysed through the average PT method using THERMOCALC are; 700-850°C and 5.8-6.8 kbar. This mineral assemblage indicates metamorphism in the area has achieved upper-arnphibolite to lower granulite facies metamorphism at some stage in the PT history of the area.
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ItemLate Cainozoic climatic and eustatic record from the Loxton-Parilla Sands, Murray Basin, Southeastern Australia( 1995)A series of ancient shoreline ridges in the western Murray Basin of southeastern Australia preserve a detailed legacy of Pliocene marine retreat. The 157 subdued NNW trending coastal ridges of the Loxton-Parilla Sands, mapped using conventional techniques and night-time thermal imagery from the NOAA and the ERS-l satellites, extend in a parallel series from 400 km inland to the present coastline, and provide a virtual contour plan of the Pliocene landscape. Coastal ridges of the Loxton-Parilla Sands range in age from 6:6 Ma in the east, to 3.5 Ma towards the west, where they are tectonically deformed by the uplift of the Pinnaroo Block. The deposition of the Loxton-Parilla Sands at 6.6 Ma is correlated with high global sea levels, with the distribution of the sands suggesting deposition at a topographic level comparable to an ice-free earth (i.e. complete deglaciation of the polar regions). Coastal ridges consist of beach-barrier and near-shore sediments deposited in conditions of fluctuating sea levels. The absence of aeolian sediments within the ridges implies a significantly weaker wind-wave regime and/or permanent vegetation cover existed throughout the Pliocene. Eustatic oscillations recognized within the shoreline sequence correlate well with glacio-eustatic changes modulated by the axial precession of the earth with a periodicity near 20, 000 years. Following retreat of the sea, the Loxton-Parilla Sands were subject to deep weathering, with the resultant profile termed the Karoonda Regolith. Following cessation of coastal deposition the Karoonda Regolith developed diachronously, with the oldest pedogenic exposures in the east to the youngest towards the west. Ferric and silicic weathering profiles developed in late Miocene to Plio-Pleistocene times. Pedogenic silcretes formed by downward movement of acidic soil waters with saturation and deposition at the soilwater-groundwater interface under alternating wet and dry conditions. High water tables probably ensured accumulation of silica in the near surface environment. By the Mid Pliocene (3.5 Ma) weathering changed from predominantly silica to iron mobilization with development of ferricrete profiles. Late Pleistocene (0.7-0.4 Ma) ferricrete development ceased when arid climates developed as represented by calcareous soils across the basin. Addition of calcareous parna on the Karoonda Regolith buffered soil water pHs, and switched off ferricrete development. Extensive opaline silica dissolution under alkaline conditions resulted in the development of karstic-type solution pipes that were infilled with pisoliths and clasts of sandstone. Lowered groundwater tables probably contributed to the removal of silica from the near-surface permitting transfer to deep aquifers within the Loxton-Parilla Sands. The change from ferricrete to calcrete formation marks the onset of arid climates in Australia. Correlatives can be drawn between this continental record of sea level changes with those of the deep sea oxygen isotope curves which reflect Milankovitch-type changes in the ice budget of the world.