Chemical and Biomolecular Engineering - Theses
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ItemShrinkage behaviour of geopolymer( 2009)Geopolymer cements offer an alternative to, and potential replacement for, ordinary Portland cement (OPC). Geopolymer technology also has the potential to reduce global greenhouse emissions caused by OPC production. There is already a considerable amount of work and research conducted on geopolymers in the past decades, and it is now possible to implement this technology commercially. However, to ensure that geopolymer becomes commercially available and able to be used in the world, further understanding of its ability to provide durable and long lasting materials is required. One main property which is still relatively unexplored compared to other properties is its shrinkage properties. The objective of this thesis is therefore to examine the shrinkage of geopolymers and factors which might influence it. The factors which influence geopolymer strength were investigated as being the factors which may influence shrinkage. The selection of the activating solution is an important factor in forming the final product of a geopolymer. Activating solution SiO2/Na2O ratio is determined to be an important influence on the shrinkage of geopolymer. SEM images of the samples enable observation of the sample topology and microstructure. An important observation was the existence of a ‘knee point’ which also occurs in OPC shrinkage. The ‘knee point’ is the point where the shrinkage goes from rapid shrinkage to slow shrinkage. From SEMs it is noted that the samples past the knee point are shown to have a smoother topology which means it is more reacted. Autogenous shrinkage is an important issue for OPC containing a high amount of silica, and is also a key factor in geopolymer shrinkage. Autogenous shrinkage is tested by keeping samples in a sealed environment where water lost to drying is kept to a minimum. It is noted that sealing and bagging the samples reduces the shrinkage considerably. The water to cement ratio, which is an important factor in OPC shrinkage, is also explored for the case of geopolymers. Water content plays an important role in determining early stage shrinkage, and has little to no effect on the later stage shrinkage. The water loss from the samples during drying on exposure to environment is noted and compared. The addition of more water did not necessary means that more water was lost. Addition of slag is known to be beneficial to geopolymers by giving early structural strength and faster setting time. Commercial geopolymer concrete will also include the use of slag. However, the addition of slag up to a certain extent gives a deleterious affect on shrinkage. A different type of Class F fly ash source with different composition data was used to see its effect on shrinkage, with only a slight influence observed between the two ashes tested. Fly ash was also ground for different lengths of time before use in geopolymerization, with grinding for less than 12 hours giving higher shrinkage than an unground sample, but shrinkage the decreasing with grinding for 18 or 24 hours. This initial higher shrinkage has been attributed to the mechanism of grinding which resulted in unevenly shaped fly ash particles taking up a larger initial volume resulting in higher shrinkage. The sample grinded for 24 hours showed higher shrinkage due to the particle size to be so fine that agglomerates may have form during mixing which would result in a lower reaction rate which increases the shrinkage. Elevated curing temperatures also reduce geopolymer shrinkage. Thus, it is clear that the shrinkage of geopolymers is influenced by a wide range of variables, and more notably by a few important variables: activating solution ratio, addition of water, grinding and bagging. The shrinkage of geopolymers can be correlated to the strength to a certain extent. However, the understanding of the shrinkage of geopolymers is still at a very initial phase, and further research is required.
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ItemRheological characterisation of nickel laterite slurry in processing environments( 2006)With China’s continuing economic boom, the demand for nickel has seen unprecedented growth over the past 10 years. Most of the world’s nickel is present in nickel laterite deposits. These high volume, low grade deposits are now being exploited and processed. An understanding of nickel laterite rheology and the ability to obtain meaningful rheological data is essential to process intensification and stability. The properties and physical characteristics of 8 industrial nickel laterite slurries as well as two alumina slurries were examined using various rheological techniques. The samples chosen covered a wide range of physical conditions such as differing pH, particle size distributions, solids densities and mineralogy as well as country and deposit of origin. The rheological parameters investigated were the yield stress and shear stress vs. shear rate of the particulate slurries. Considerable attention was focused on the techniques used in shear stress vs. shear rate characterisation, including capillary rheometry, smooth and roughened cup and bob rheometry and the vane in infinite medium technique. This work confirmed the finding of previous works, showing nickel laterite slurry rheological behaviour ranging from time independent to thixotropic to rheopectic. It found the vane in infinite medium technique highly suitable for testing nickel laterites at process relevant yield stresses. This technique gave data that correlated well with vane yield stresses and capillary rheometry data. Cup and bob tests showed significant slip at lower shear rates. In a number of cases, the cup and bob techniques also showed erroneously high stresses at higher shear rates. The vane yield stress was found to be a fast and accurate method for monitoring nickel laterite sample aging and the samples tested exhibited 100 Pa yield stresses at solids fractions ranging from 0.389 to 0.524. Blending of nickel laterites was found to be nonlinear, and confirmed that characterisation at various blend ratios is necessary if blending is to be utilised during production.