School of Historical and Philosophical Studies - Research Publications

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    A preliminary investigation into the influence of archaeological material on the yellowing of polyethylene storage bags
    Thompson, K ; Nel, P (Routledge, 2021)
    Concerns around the degradation of plastics have been part of conservation discourse for decades. The spotlight is usually on art and objects, and conservation and display materials, however it could be argued that a significant volume of the plastics in museums is associated with storage bags. This study asked whether the condition of plastic storage bags might be influenced by what is stored inside them. If specific materials can be identified as more likely to affect plastic degradation, museums may have a lead-indicator for efficiently monitoring storage risks. This case study developed a methodology for applying multivariate analysis to collected data to answer this question. A subset of polyethylene self-seal bags used to pack archaeological material from the ‘Casselden Place’ assemblage at Museums Victoria was evaluated. Objective data were combined with subjective assessment of bag degradation features gathered during a collection survey and interrogated using multivariate statistical analysis. Results indicate (1) different levels of yellowing are associated with particular plastic bag stocks and (2) ceramic, slate and tile finds are more likely than other materials to be contained within yellower bags. The research points to future enquiry and demonstrates this methodology shows promise for extension to other large cultural datasets.
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    Surveys of Plastics in Post-1950 Non-published Book Collections
    Chu, C ; Barrett, M ; Bunn, S ; Zilio, F ; Bell, J ; Nel, P (De Gruyter, 2023-03-03)
    Research over the past three decades has demonstrated that certain plastics in cultural materials are inherently unstable, displaying short lifespans and accelerating the degradation of neighbouring collection materials. Knowledge of the conservation of plastics is increasingly common in museum settings. However, less information is available on conserving plastics found in paper-based collections, and even less guidance on the materials and deterioration of plastic components found in book and document bindings. As plastics have been present in popular bookbinding materials since the mid-twentieth century, collection care professions require knowledge and methods for preserving these materials entering book collections. The aim of this paper is to determine strategies for the care of post-1950s books containing plastic. Collection surveys were conducted to determine the materials, structures, and degradation patterns of non-published books found in archive and archive-like settings at the South Australian Museum, the Art Gallery of New South Wales, and the Grimwade Centre for Cultural Materials Conservation at the University of Melbourne. A methodology combining condition reporting and infrared spectroscopy identified six plastic polymers in 35 binding styles that are summarised as 10 binding types. Recommendations are made for the use of preventive storage strategies responding to four categories of damage.
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    Identification of polymer-based artefacts from the former Wheeler Residence at the Mernda archaeological site in Victoria, Australia: A comparison of attenuated total reflectance and reflectance spectroscopic techniques
    Wong, SSH ; Stuart, B ; Kim, C ; Nel, P (International Council of Museums, 2021)
    The purpose of this investigation was to identify the polymers in artefacts recovered from archaeological excavations at the former Wheeler Residence using attenuated total reflectance Fourier transform infrared and reflectance spectroscopy. The results from both techniques are compared and discussed. Identification will assist with the long-term management and storage of these polymer-based artefacts. Evaluation of these two sampling techniques included whether the physical characteristics and polymer type of the artefacts favoured the use of one technique over the other. The inherent challenges of archaeological artefacts such as cataloguing conventions, awkwardly shaped fragments and soil encrustations complicated the analysis. Of the 270 samples analysed, 67% were identified as containing ten different types of polymers, with the remaining 33% consisting of unidentified polymers, encrusted polymers in which only soil bands or other materials such as glass were identified. Although reflectance achieved better results for certain types of artefacts, it also revealed limitations. The identified polymers are compatible with the proposed occupation of the site from 1852 to the 1970s.
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    Should we clean plastics like we clean paintings? A study in cleaning plasticised poly (vinyl chloride)
    Nel, P ; Morrison, J ; Rowe, S (University of Cambridge Museums, 2023)
    Cleaning plastics poses a significant issue in cultural collections. Highly susceptible to attack from mech- anical, organic and ionic cleaning agents, it can seem impossible to find products that adequately clean plastic materials without causing damage in the process. This paper aims to address these issues. It explores how techniques, knowledge and decision-making processes used in painting conservation can be adapted and used to deliver sophisticated, inexpensive, and accessible strategies for cleaning plastics. Using plasticised polyvinyl chloride as a case study, this paper demonstrates how principles of pH, ion concentration, polarity, chelation, gel-formulations and colloidal interface can be used to arrive at optimal methods for cleaning plastics. Combinations of Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR), optical microscopy, colourimetry and accelerated ageing were used to determ- ine the effectiveness of and damage levels of the cleaning processes being evaluated. Ultimately it was found that neat solvents, detergents and acidic or basic aqueous solutions should not be used unaltered but should rather be tailored specifically to the needs of the polymeric material being treated.
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    Investigating the efficacy of interleaving materials in the preservation of plasticised PVC slip-cover notebooks in Yang Zhichao’s artwork Chinese Bible
    Chu, C ; Bunn, S ; Barrett, M ; Nel, P (Routledge, 2022-10)
    Plasticised poly(vinyl chloride) (PVC-P) is known to degrade rapidly and emit acidic gases and, as such, it is ideally stored separately from other materials. However, due to historic or aesthetic value, PVC-P book covers in paper-based collections cannot always be removed or replaced. There is currently a gap in the literature addressing strategies for storing PVC-P associated with paper materials. Prompted by a case study of the Chinese artist Yang Zhichao’s Chinese Bible (2009)—a performance installation artwork of 3000 notebooks including approximately 1000 notebooks with PVC-P covers—three potential interleaving materials (Mylar®, Hollytex® and buffered tissue) were tested to simulate use during long-term storage. Notebooks and PVC-P book covers were purchased and assembled to model stacked storage conditions, and thermally aged at 70°C and 50% relative humidity for 130 days. Before and after ageing, samples were analysed using visual examination techniques, ATR-FTIR spectroscopy, colourimetry and weighing. It was found that all three interleaving materials lowered the probability of ink offsetting. However, cover deformation and a blotchy surface haze were more commonly observed in interleaved samples compared to non-interleaved samples. More research is necessary to identify a suitable strategy to manage PVC-P degradation in close contact storage with paper materials. This study contributes to a better understanding of the storage of plastic-covered books that may be found in libraries and archives, highlighting the complexity of conserving plastic and paper composite materials.
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    Safe Storage? An Assessment of Polyethylene for the Storage of Heritage Objects
    Stuart, B ; Wong, S ; Goodall, R ; Beale, A ; Chu, C ; Nel, P ; Amin-Jones, H ; Thomas, P (ROUTLEDGE JOURNALS, TAYLOR & FRANCIS LTD, 2023-08-18)
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    Collaborative Development of Polymer-Based Collection Survey Methodology and Relational Data Model
    Bell, J ; Thompson, KM ; Palmer, K ; McCarthy, G ; Barrett, M ; Burrows, E ; Nel, P (ROUTLEDGE JOURNALS, TAYLOR & FRANCIS LTD, 2022-08-10)
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    Conservation and characterization of arabic papyrus in Egyptian National Library and Archives, Egypt
    Mohamed, A ; Nel, P ; Wahba, W ; Kamel, A ; Sloggett, R (IOP Publishing, 2020-11-10)
    An Ara bic Pa pyrus sheet stored a t the Egyptia n Na tiona l Libra ry a nd Archives wa s previously pla ced on unknown seconda ry support, a nd interlea ved between two gla ss sheets enclosed with a dhesive ta pe. This pa pyrus ha s various deteriora tion issues especia lly in the upper section where there is a la rge embedded sta in ca using the pa pyrus to stick to the secondary support a nd the gla ss sheet. Conserva tion trea tments conducted involved clea n ing, fibre a lignment a nd rehousing, scientific investiga tions including visible light microscopy, Fourier tra nsform infra red spectroscopy with a ttenua ted tota l reflecta nce (FTIR-ATR), a nd Sca nning Electron Microscopy with Energy Dispersive Spectrometry (SEM-EDS) were conducted to identify ma teria ls involved. A la ck of informa tion in the historica l records a bout the exca vation a nd previous conserva tion trea tments increa se the importa nce of the resea rch. The a na lysis showed tha t the seconda ry support is gela tine a nd Ara bic text wa s written in ca rbon ink. The gela tine support wa s successfully removed from the pa pyrus a nd the pa pyrus document wa s re - housed.