School of Historical and Philosophical Studies - Research Publications

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Author: Nel, Petronella × Author: Noake, Emily ×

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    Identification of cellulose nitrate based adhesive repairs in archaeological pottery of the University of Melbourne's Middle Eastern archaeological pottery collection using portable FTIR-ATR spectroscopy and PCA
    Noake, E ; Lau, D ; Nel, P (BMC, 2017-01-19)
    A previous study of the Cypriot pottery collection housed in the Ian Potter Museum of Art at the University of Melbourne found approximately two-thirds of adhesive repairs are primarily composed of cellulose nitrate (CN). This is of concern as CN has a limited lifespan (6–20 years), which has implications for the strategic management of the collection. To gain a greater understanding of the prevalence of CN based adhesive repairs in the archaeological context, the original FTIR-ATR spectroscopic survey was extended to incorporate the University’s Middle Eastern archaeological pottery collection. Micro-samples were removed from artefacts using acetone swabs. Analysis of adhesive FTIR spectra identified CN to be present not only as the primary polymer in approximately one-tenth of repairs, but also as a secondary polymer in poly(vinyl acetate) (PVAc) and acrylic adhesive formulations, observed as a weak peak at ~1656 cm−1. CN’s secondary presence in PVAc adhesive formulations is demonstrated using principal component analysis (PCA) and the diphenylamine spot test for CN. Re-analysis of adhesive IR spectra from the Cypriot pottery collection found CN to be present as a secondary polymer in this collection as well. It is concluded a combined methodology of collecting and identifying FTIR-ATR spectra of adhesive repairs from archaeological pottery collections followed by PCA analysis bring to light adhesive formulations which can inform the management of pottery collections.
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    Identification of issues associated with finding polystyrene repairs on archaeological pottery
    NEL, P ; Noake, E ; Jones-Amin, H ; McKenna, E (International Council of Museums, 2014)
    At the University of Melbourne, an adhesive iden- tification survey using FTIR-ATR spectroscopy of 146 repaired Cypriot pottery vessels revealed polystyrene on five artefacts. This unexpected polystyrene finding raised concern about why it was present and how it may have contributed to the current condition of the vessels it was associ- ated with. Comprehensive analysis and mapping of polystyrene distribution on a vessel composed of 30 pieces revealed the adhesive to be present on numerous sherd edges, consistent with it being used as an adhesive. A new set of solvent param- eters was established for reversing brittle unstable conjoins of an adhesive not previously discussed or considered in ceramics conservation. These findings demonstrate the importance of accurate adhesive identification in planning successful treat- ments and the value of using portable analytical equipment for identifying adhesives otherwise not detectable using standard visual and ultraviolet fluorescence examination methods.