Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp(3))-H bond functionalisation

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    Author
    Czyz, ML; Weragoda, GK; Horngren, TH; Connell, TU; Gomez, D; O'Hair, RAJ; Polyzos, A
    Date
    2020-03-07
    Source Title
    Chemical Science
    Publisher
    ROYAL SOC CHEMISTRY
    University of Melbourne Author/s
    Polyzos, Anastasios; Czyz, Milena; O'Hair, Richard; Gomez, Daniel
    Affiliation
    School of Chemistry
    School of Physics
    Metadata
    Show full item record
    Document Type
    Journal Article
    Citations
    Czyz, M. L., Weragoda, G. K., Horngren, T. H., Connell, T. U., Gomez, D., O'Hair, R. A. J. & Polyzos, A. (2020). Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp(3))-H bond functionalisation. CHEMICAL SCIENCE, 11 (9), pp.2455-2463. https://doi.org/10.1039/c9sc05722f.
    Access Status
    Open Access
    URI
    http://hdl.handle.net/11343/252313
    DOI
    10.1039/c9sc05722f
    ARC Grant code
    ARC/IC170100020
    Abstract
    <p>Visible light irradiation of 8-aminoquinoline Pd(<sc>ii</sc>) complexes initiates photoinduced electron transfer with alkyl halides, affording C–H halogenation over C–C bond adducts. A method for inert C(sp<sup>3</sup>)–H bond halogenation (Br, Cl and I) is reported.</p>

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