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    Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp(3))-H bond functionalisation

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    Author
    Czyz, ML; Weragoda, GK; Horngren, TH; Connell, TU; Gomez, D; O'Hair, RAJ; Polyzos, A
    Date
    2020-03-07
    Source Title
    Chemical Science
    Publisher
    ROYAL SOC CHEMISTRY
    University of Melbourne Author/s
    Polyzos, Anastasios; Czyz, Milena; O'Hair, Richard; Gomez, Daniel
    Affiliation
    School of Chemistry
    School of Physics
    Metadata
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    Document Type
    Journal Article
    Citations
    Czyz, M. L., Weragoda, G. K., Horngren, T. H., Connell, T. U., Gomez, D., O'Hair, R. A. J. & Polyzos, A. (2020). Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp(3))-H bond functionalisation. CHEMICAL SCIENCE, 11 (9), pp.2455-2463. https://doi.org/10.1039/c9sc05722f.
    Access Status
    Open Access
    URI
    http://hdl.handle.net/11343/252313
    DOI
    10.1039/c9sc05722f
    ARC Grant code
    ARC/IC170100020
    Abstract
    <p>Visible light irradiation of 8-aminoquinoline Pd(<sc>ii</sc>) complexes initiates photoinduced electron transfer with alkyl halides, affording C–H halogenation over C–C bond adducts. A method for inert C(sp<sup>3</sup>)–H bond halogenation (Br, Cl and I) is reported.</p>

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