Observation and ultrafast dynamics of a nonvalence correlation-bound state of an anion
AuthorBull, JN; Verlet, JRR
Source TitleScience Advances
PublisherAMER ASSOC ADVANCEMENT SCIENCE
University of Melbourne Author/sBull, James
AffiliationSchool of Chemistry
Document TypeJournal Article
CitationsBull, J. N. & Verlet, J. R. R. (2017). Observation and ultrafast dynamics of a nonvalence correlation-bound state of an anion. SCIENCE ADVANCES, 3 (5), https://doi.org/10.1126/sciadv.1603106.
Access StatusOpen Access
Nonvalence states of molecular anions play key roles in processes, such as electron mobility, in rare-gas liquids, radiation-induced damage to DNA, and the formation of anions in the interstellar medium. Recently, a class of nonvalence bound anion state has been predicted by theory in which correlation forces are predominantly responsible for binding the excess electron. We present a direct spectroscopic observation of this nonvalence correlation-bound state (CBS) in the para-toluquinone trimer cluster anion. Time-resolved photoelectron velocity map imaging shows that photodetachment of the CBS produces a narrow and highly anisotropic photoelectron distribution, consistent with detachment from an s-like orbital. The CBS is bound by ~50 meV and decays by vibration-mediated autodetachment with a lifetime of 700 ± 100 fs. These states are likely to be common in large and/or polarizable anions and clusters and may act as doorway states in electron attachment processes.
- Click on "Export Reference in RIS Format" and choose "open with... Endnote".
- Click on "Export Reference in RIS Format". Login to Refworks, go to References => Import References