Tolerant to air sigma-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

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    Author
    Bukvic, AJ; Crivoi, DG; Garwood, HG; McKay, A; Chen, TTD; Martinez-Martinez, AJ; Weller, AS
    Date
    2020-04-21
    Source Title
    Chemical Communications
    Publisher
    ROYAL SOC CHEMISTRY
    University of Melbourne Author/s
    McKay, Alasdair
    Affiliation
    School of Chemistry
    Metadata
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    Document Type
    Journal Article
    Citations
    Bukvic, A. J., Crivoi, D. G., Garwood, H. G., McKay, A., Chen, T. T. D., Martinez-Martinez, A. J. & Weller, A. S. (2020). Tolerant to air sigma-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer. CHEMICAL COMMUNICATIONS, 56 (31), pp.4328-4331. https://doi.org/10.1039/d0cc01140a.
    Access Status
    Open Access
    URI
    http://hdl.handle.net/11343/274156
    DOI
    10.1039/d0cc01140a
    Abstract
    Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BArF4]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.

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