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dc.contributor.authorHill, MR
dc.contributor.authorBastow, TJ
dc.contributor.authorBourgeois, L
dc.contributor.authorTurner, DR
dc.contributor.authorSeeber, A
dc.contributor.authorMcBean, K
dc.contributor.authorWhitfield, HJ
dc.date.available2014-05-22T08:30:31Z
dc.date.issued2012-01-01
dc.identifierhttp://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000302737600011&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=d4d813f4571fa7d6246bdc0dfeca3a1c
dc.identifier.citationHill, M. R., Bastow, T. J., Bourgeois, L., Turner, D. R., Seeber, A., McBean, K. & Whitfield, H. J. (2012). A simple route to full structural analysis of biophosphates and their application to materials discovery. DALTON TRANSACTIONS, 41 (18), pp.5497-5501. https://doi.org/10.1039/c2dt00023g.
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/11343/33259
dc.descriptionC1 - Journal Articles Refereed
dc.description.abstractAn integrated suite of synthesis and characterisation techniques that includes synchrotron-based single crystal, powder X-ray diffraction, nuclear magnetic resonance and electron diffraction have been employed to uncover two new distinct structures in the Ca(x)Ba(2-x)P(2)O(7) polymorphic phosphate system. These materials have particular relevance for their application as both biomaterials and phosphors. Calcium barium pyrophosphate, CaBaP(2)O(7), was shown by a combination of spectroscopic and diffraction techniques to have two polymorphs distinct in structure from all of the five previously reported polymorphs of Ca, Sr and Ba pyrophosphate. A high temperature polymorph HT-CaBaP(2)O(7) prepared at 1200 °C is orthorhombic, of space group P(212121) with a = 13.0494 Å, b = 8.9677 Å, c = 5.5444 Å. A low temperature polymorph LT-CaBaP(2)O(7), prepared below 1000 °C, is monoclinic with space group P2(1)/c and dimensions a = 12.065 Å, b = 10.582 Å, c = 9.515 Å, β = 94.609°.
dc.languageEnglish
dc.publisherROYAL SOC CHEMISTRY
dc.subjectTransition Metal Chemistry; Expanding Knowledge in the Chemical Sciences
dc.titleA simple route to full structural analysis of biophosphates and their application to materials discovery
dc.typeJournal Article
dc.identifier.doi10.1039/c2dt00023g
melbourne.peerreviewPeer Reviewed
melbourne.affiliationThe University of Melbourne
melbourne.affiliation.departmentChemistry
melbourne.source.titleDALTON TRANSACTIONS
melbourne.source.volume41
melbourne.source.issue18
melbourne.source.pages5497-5501
melbourne.publicationid197179
melbourne.elementsid446029
melbourne.contributor.authorHILL, MATTHEW
dc.identifier.eissn1477-9234
melbourne.accessrightsThis item is currently not available from this repository


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