A new fluorone-based bridging ligand for discrete and polymeric assemblies including Mo and W based [4+4] metallocycles
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2020-07-21
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New Journal of Chemistry
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Royal Society of Chemistry
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School of Chemistry
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Journal Article
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Sutton, A. L., Abrahams, B. F., Hudson, T. A. & Robson, R. (2020). A new fluorone-based bridging ligand for discrete and polymeric assemblies including Mo and W based [4+4] metallocycles. New Journal of Chemistry: a journal for new directions in chemistry, 44 (27), pp.11437-11440. https://doi.org/10.1039/d0nj02413a.
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Abstract
Redox-active ligands are of interest for their ability to link metal centres and generate electroactive materials. We report the synthesis of 9-hydrogen-2,3,7-trihydroxyfluorone, which is able to serve as a bridging ligand and has the potential to exist in multiple oxidation states. Anionic [4+4] metallocycles in which Mo or W centres are linked by the trianion of this ligand are also described.